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ExxonMobil Refinery (2638), Baton Rouge

Releases in 2009

LDEQ Accident Number
Accident Date
Point Source/Release CauseNotes
120247

2009-12-17
Point Source(s):
flare

Pollutant(s):
No Information Given - 0
Cause of Problem: Process Upset

Flaring occurred.
RQ not exceeded.
No LDEQ Number Available

2009-12-08
Point Source(s):
Outfall 003

Pollutant(s):
Oil - 0 pounds
Cause of Problem: Weather

The large volume of water after a heavy rainfall resulted in an oil sheen. Oil was release through Outfall 003 into bayou. The size and color of the sheen indicated a release of less than 1/4 gallon of oil.
Release is BRQ.
119868

2009-12-05
Point Source(s):
flange

Pollutant(s):
Oil - 118 pounds
Cause of Problem: Maintenance/Procedures

Flange failure occurred during a hydrocarbon freeing procedure prior to performing maintenance on the unit. The flange failed after steam injection had been initiated, per procedure. Crude oil released exceeded RQs.
RQ exceeded. Vacuum trucks recovered material. Flange will be repaired.
119907

2009-12-05
Point Source(s):
NIG

Pollutant(s):
Naphthalene - BRQ
Cause of Problem: Piping or Tubing

Leak occurred on piping.
Release is BRQ. There is a date difference on company report (Dec. 5, 2009) and State Police HAZMAT report (Dec. 7, 2010).
119856

2009-12-04
Point Source(s):
T2-61A

Pollutant(s):
Propylene - BRQ
Ethylene - BRQ
Hydrogen Sulfide - BRQ
Cause of Problem: Seal or Gasket

Pump seal leak on T2-61A.
LDEQ report states "propylene, ethylene, H2S and benzene expected to exceed reportable quantities. ExxonMobil in its report states that reportable quantities were not exceeded. Isolated the leak.
119908

2009-12-04
Point Source(s):
frac tank

Pollutant(s):
Oil - 958 pounds
Cause of Problem: Instrument Failure

Level gauge on frac tank failed as tank was being water rinsed in preparation for chemical cleaning.
RQ exceeded. Water rinse pumps stopped and area barricaded. Vacuum trucks recovered the material. Level on frac tank repaired. Procedures will be adjusted to include visual level verifications. Contaminated soil removed.
119723

2009-11-27
Point Source(s):
No information given.

Pollutant(s):
Crude Oil - BRQ
Cause of Problem: Process Upset

Unit instability caused a unit upset which resulted in the release.
Release is BRQ. Unit will be shut down.
No LDEQ Number Available

2009-11-27
Point Source(s):
No Information Given

Pollutant(s):
Crude Oil - BRQ
Cause of Problem: Process Upset

Unit instability.
Company letter missing. RQ not exceeded. Unit will be shut down.
119697

2009-11-24
Point Source(s):
NIG

Pollutant(s):
No Information Given - BRQ
Cause of Problem: Piping or Tubing

Leak occurred. No further information provided.
RQ not exceeded. LABB only has access to refinery report.
119501

2009-11-16
Point Source(s):
flares

Pollutant(s):
Sulfur Dioxide - BRQ
Nitric Oxide - BRQ
Butadiene - BRQ
Cause of Problem: Equipment Failure

Compressor tripped at RGC unit.
RQ not exceeded. Will re-start compressor and minimize gas that will be sent to the flare.
127398

2009-11-03
Point Source(s):
No Information Given

Pollutant(s):
Benzene - BRQ
Volatile Organic Compounds (VOCs) - BRQ
Xylene - BRQ
Flammable Gas - BRQ
Cause of Problem: Piping or Tubing

There was a pinhole leak in a pipe releasing benzene, VOC, xylene, and flammable gas.
The Unit was Shut Down. Below Reportable Quantities
119077

2009-10-28
Point Source(s):
transfer piping

Pollutant(s):
Oil - 88 pounds
Cause of Problem: Corrosion

Failure of transfer piping crude tankage from corrosion.
RQ exceeded. Pipe isolated and replaced. Contaminated soil removed.
No LDEQ Number Available

2009-10-20
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - 0
Cause of Problem: Piping or Tubing

leak occurred.
RQ not exceeded.
No LDEQ Number Available

2009-10-20
Point Source(s):
No Information Given

Pollutant(s):
Hydrocarbon - BRQ
Cause of Problem: Maintenance/Procedures

Sample taken showed potential for hydrocarbon leak.
Company letter missing. Verbal report. RQ not exceeded.
118829

2009-10-17
Point Source(s):
transfer piping

Pollutant(s):
Xylene - 24,759 pounds
Toluene - 14,845 pounds
Ethylbenzene - 4,024 pounds
Naphthalene - 1,527 pounds
Benzene - 2,521 pounds
n-Hexane - 9,525 pounds
Cyclohexane - 1,040 pounds
2,2,4-Trimethylpentane - 13,217 pounds
Volatile Organic Compounds (VOCs) - 296,468 pounds
Flammable Vapor - 37,086 pounds
Oil - 57,330 pounds
Cause of Problem: Corrosion

Failure of line of transfer piping from gasoline tankage to loading line due to corrosion at the air-soil interface of piping.
RQ exceeded. Isolated line with blind installation. Replaced with new piping and special program has been initiated to emphasis piping that may be subject to air-soil interface corrosion. Contaminated soil removed. The refinery letter misstates that the accident occurred on 08/21/09. The following RQs were exceeded: xylene, toulene, ethylbenzene, napthalene, benzene, n-hexane, cyclohexane, 2,2,4-trimethylpentane, VOCs, oil to soil, and flammable vapor.
118665

2009-10-12
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: Piping or Tubing

Leak occurred.
RQ not exceeded. LABB only has access to refinery report.
118656

2009-10-11
Point Source(s):
No Information Given

Pollutant(s):
Hydrogen - BRQ
Cause of Problem: Equipment Failure

Hydrogen compressor for the hydrocracker had a bladder rupture.
RQ not exceeded. Situation secured.
118637

2009-10-10
Point Source(s):
No Information Given

Pollutant(s):
Hydrocarbon - BRQ
Cause of Problem: Piping or Tubing

Sample showed potential for hydrocarbon leak. No further information provided.
RQ not exceeded. Sheen was observed in final containment, but none was discarhged into the Mississippi River.
119021

2009-10-10
Point Source(s):
spent catalyst line

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: Piping or Tubing

Leak occurred in spent catalyst lines.
RQ not exceeded. Evaluating to make repairs.
118272

2009-09-28
Point Source(s):
Flare # 17 and 19

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: No Information Given

Flare #17 and #19 ignited due to an unknown reason
RQ not exceeded.
118103

2009-09-22
Point Source(s):
No Information Given

Pollutant(s):
Benzene - BRQ
Cause of Problem: Piping or Tubing

Leak into cooling tower.
RQ not exceeded. Isolating exchanger to determine leaking substance.
118014

2009-09-16
Point Source(s):
channel box

Pollutant(s):
Light Cycle Oil - BRQ
Cause of Problem: Piping or Tubing

Light cyclic oil leak found on channel box.
Release is BRQ. Exxon turned steam ring off and raised temperature to stop leak.
117931

2009-09-13
Point Source(s):
Flare #17 and #19

Pollutant(s):
Hydrocarbon - BRQ
Cause of Problem: Equipment Failure

A problem with the hydrocracking unit caused flaring.
Release is BRQ. No further information provided.
117870

2009-09-11
Point Source(s):
FLARE

Pollutant(s):
Hydrogen - BRQ
Cause of Problem: Process Upset

Safety release flaring. No further information provided.
Release is BRQ. No further information provided.
117816

2009-09-09
Point Source(s):
No Information Given

Pollutant(s):
Reformate - BRQ
Heavy Oil - BRQ
Cause of Problem: Seal or Gasket

Small fire occurred due to flange leak on control valve. of heavy oil
Release is BRQ. Fire was extinguished and leak was controlled.
117813

2009-09-07
Point Source(s):
No Information Given

Pollutant(s):
Carbon Monoxide - 489 pounds
Cause of Problem: Process Upset

PCLA unit in the F201 furnace was upset.
Release is BRQ. LABB only has access to LDEQ and SPOC reports.
117818

2009-09-07
Point Source(s):
pipe

Pollutant(s):
Polycyclic Aromatic Hydrocarbons - 2 pounds
Oil - 239 pounds
Cause of Problem: Piping or Tubing

Leak from pipe near Ave I and 16th Street.
Release exceeded RQs. Line isolated and vacuum truck recovered majority of release. Line will be replaced with flanged spool piece. Contaminated soil will be removed.
117732

2009-09-04
Point Source(s):
No Information Given

Pollutant(s):
Hydrogen Sulfide - 576 pounds
Cause of Problem: Piping or Tubing

A pinhole leak was found and repaired.
Release is BRQ.
117482

2009-08-25
Point Source(s):
FLARE

Pollutant(s):
Hydrogen - BRQ
Cause of Problem: Equipment Failure

Hydrogen compressor leaked which caused flaring.
Release is BRQ. Compressor was de-pressurized to stop flaring.
117459

2009-08-22
Point Source(s):
no information given

Pollutant(s):
Sulfur Dioxide - BRQ
Nitrogen Oxide - BRQ
Nitrogen Dioxide - BRQ
Hydrogen Sulfide - BRQ
Cause of Problem: Equipment Failure

Compressor malfunctioned leading to flares.
RQ not exceeded. Company reports and State Police HAZMAT report differs in pollutants.
117415

2009-08-21
Point Source(s):
insulated dead leg pipe

Pollutant(s):
Polycyclic Aromatic Hydrocarbons - 5 pounds
Oil - 168 pounds
Cause of Problem: Corrosion

Leak from corrosion in insulated dead leg pipe.
Release is above RQs. Line isolated and insulation stripped from piping. A clamp was placed over leaking section. Contaminated soil removed. Long term solution is being determined.
117187

2009-08-10
Point Source(s):
cooling tower

Pollutant(s):
Propane - BRQ
Cause of Problem: Equipment Failure

A cooling tower leaked propane.
Release is BRQ. Fixed leak.
No LDEQ Number Available

2009-08-07
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred but information provided about cause.
The release of unspecified material is BRQ. LABB only has access to the refinery report.
117096

2009-08-06
Point Source(s):
No Information Given

Pollutant(s):
Butene - BRQ
Butylene - BRQ
Isobutylene - BRQ
Cause of Problem: Piping or Tubing

Leak occurred, but no information provided about the cause.
Release is BRQ. Secured leak and will de-pressurize line then replace pipe. LABB does not have access to the LDEQ incident report.
117109

2009-08-06
Point Source(s):
NIG

Pollutant(s):
Ammonia - 0
Cause of Problem: Power Failure

Unit section lost power and caused ammonia compressor to lose power which resulted in flaring.
Odor present. LABB only has access to the SPOC report. No information provided on whether release was BRQ.
117013

2009-08-04
Point Source(s):
No Information Given

Pollutant(s):
Hydrogen Sulfide - BRQ
Cause of Problem: Equipment Failure

A leak occurred in a cooling tower where the discharge goes to water treatment system on site.
Release is BRQ. Incident may be caused by different water cooling tower which is still under investigation.
No LDEQ Number Available

2009-08-03
Point Source(s):
No information given.

Pollutant(s):
No Information Given - BRQ
Cause of Problem: Piping or Tubing

Leak occurred.
RQ not exceeded.
116863

2009-07-28
Point Source(s):
flare system

Pollutant(s):
Sulfur Dioxide - 1,161 pounds
Nitrogen Oxide - BRQ
Volatile Organic Compounds - BRQ
Benzene - BRQ
Hydrogen Sulfide - BRQ
Cause of Problem: Start Up, Shut Down

PCLA-2 Fluid Catalytic Cracking Unit restart caused discharge. Unit unexpectedly shutdown earlier in the day. Restart caused pressure to build and ultimately flaring.
RQ for SO2 exceeded. State Police HAZMAT report and company reports differ in pollutants. Feed was reduced o the unit, temperatures within unit was decreased and compressor was restarted.
116840

2009-07-28
Point Source(s):
Alkyl Unit

Pollutant(s):
Sulfuric Acid - BRQ
2,3,4-Trimethylpentane - BRQ
Butene - BRQ
Volatile Organic Compounds (VOCs) - BRQ
Cause of Problem: Piping or Tubing

Ongoing pinhole leak in piping in Alkyl Unit.
RQ not exceeded. Blocked the hole, but continues to leak gas.
116811

2009-07-27
Point Source(s):
Oil-Water Separator

Pollutant(s):
F037 Hazardous Waste - 15 pounds
Cause of Problem: Weather

Due to heavy rainfall, the Oil-Water Separator at QAL overflowed.
RQ exceeded. Vacuum truck and absorbent pads recovered the material. Contaminated soil was disposed of. Tank levels will be monitored more closed in the future.
116649

2009-07-21
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided about the cause.
The RQ for an unspecified material was not exceeded. LABB only has access to the LDEQ incident report.
116539

2009-07-17
Point Source(s):
7 unspecified flares
7 flares

Pollutant(s):
Sulfur Dioxide - BRQ
Nitrogen Oxide - BRQ
Hydrogen Sulfide - BRQ
Cause of Problem: Equipment Failure

Compressor lost which caused flaring for 7 of the flares.
RQ not exceeded.
116531

2009-07-15
Point Source(s):
Outfall 003

Pollutant(s):
Oil (Sheen) - 0 pounds
Cause of Problem: Weather

There was a rain storm that lasted 1 hour and 15 minutes and produced 3.5 inches of rain. During this time, an estimated 1/8 of a gallon of oil was released into the treatment system and thus spilt through Outfall 003 into Callahan's Bayou. The oil sheen was 20'x30' and dissolved as it went with the current.
RQ not exceeded.
116430

2009-07-14
Point Source(s):
unspecified flare

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: Equipment Failure

Coker compressor failed which caused flares to burn.
RQ not exceeded.
116397

2009-07-13
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided about the cause.
RQ not exceeded for an unspecified material. LABB only has access to the refinery report.
116421

2009-07-11
Point Source(s):
No Information Given

Pollutant(s):
Naphthalene - 0
Phenanthrene - 0
Fluoranthene - 0
Cause of Problem: No Information Given

A leak occurred due to an unknown cause.
Tank emptied and remediated contaminated soil. LABB only has access to the SPOC verbal report. No information provided whether release was BRQ.
116327

2009-07-09
Point Source(s):
No Information Given

Pollutant(s):
Butane - 0
Cause of Problem: Piping or Tubing

A Leak occurred on a line in the refinery.
RQ potentially exceeded. After De-pressurizing and putting water on it, the situation was under control. LABB only has access to the SPOC verbal report. No information provided about how much material was released.
116294

2009-07-07
Point Source(s):
flare system

Pollutant(s):
Volatile Organic Compounds (VOCs) - 5,000 pounds
Ethylene - 100 pounds
Propylene - 100 pounds
Sulfur Dioxide - 500 pounds
Hydrogen Sulfide - 100 pounds
Nitrogen Oxide - 1,000 pounds
Cause of Problem: Process Upset

Safety valve lifted in the plant which caused 6 different flares to ignite.
This release estimate exceeds RQs. The incident was secured. LABB only has access to the SPOC verbal report, and all of these quantities are the initial estimates.
116296

2009-07-07
Point Source(s):
NIG

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

No information provided about the cause of the material released as a result of this incident.
The release of an unspecified material is BRQ. LABB only has access to the refinery report.
No LDEQ Number Available

2009-07-07
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information about cause of incident.
The release of an unspecified material is BRQ. LABB only has access to the refinery report.
116052

2009-06-27
Point Source(s):
No Information Given

Pollutant(s):
Flammable Gas - BRQ
Volatile Organic Compounds - BRQ
Benzene - BRQ
Cause of Problem: Piping or Tubing

Leak occurred in coker from thermowell.
RQ not exceeded.
115976

2009-06-25
Point Source(s):
seal on Tank 797

Pollutant(s):
Oil - 92 pounds
Cause of Problem: Seal or Gasket

Seal failure from the Tk-797 mixer occurred.
RQ not exceeded. Container put in place to collect leaking material. Vacuum truck put in place to recover material from container and ensure container did not overflow to soil. Will remove mixer seal and replace.
115284

2009-05-26
Point Source(s):
No Information Given

Pollutant(s):
Benzene - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information regarding the cause.
In the SPOC verbal report, Exxon indicated that the individual condensers were isolated to determine source of leak. This release is BRQ. LABB does not have access to the LDEQ incident report.
115217

2009-05-26
Point Source(s):
No Information Given


Pollutant(s):
Volatile Organic Compounds (VOCs) - BRQ
Benzene - BRQ
Cause of Problem: Piping or Tubing

Leak occurred under tower insulation in piping.
Initial reports indicate that release of VOCs and Benzene could exceed RQ, but refinery letter assures the release was BRQ.
115216

2009-05-22
Point Source(s):
No Information Given

Pollutant(s):
Benzene - BRQ
Cause of Problem: Process Upset

The PV vent is venting due to high pressure and a safety valve release.
The SPOc verbal report indicates that this release occurred on 05/24/09, but the refinery report states that the report occurred on 05/22/09. This release is BRQ.
115170

2009-05-21
Point Source(s):
No Information Given

Pollutant(s):
Hydrogen Sulfide - BRQ
Cause of Problem: Maintenance/Procedures

According to the SPOC verbal report, a release occurred at ground level due to equipment cleaning.
This release is BRQ.
115082

2009-05-19
Point Source(s):
pressure relief valves
pressure relief valve

Pollutant(s):
Volatile Organic Compounds (VOCs) - 94,114 pounds
Hydrogen Sulfide - 3,415 pounds
Benzene - 275 pounds
Cause of Problem: Instrument Failure

An Unexpected shutdown of a hydrocracker was caused by a failed thermocouple. The thermocouple failed, resulting in a low temperature reading, but then began reading erroneously high. The false high temperature reading resulted in the automatic emergency shutdown of the hydrocracking unit. The thermocouple is connected to the emergency shutdown to protect the unit from temperature runaway. The shutdown device reacted as designed.
Unit was shutdown and area secured. The RQs for flammable vapor, VOCs, H2S, and benzene was exceeded.
114924

2009-05-12
Point Source(s):
flare system

Pollutant(s):
Sulfur Dioxide - 836 pounds
Volatile Organic Compounds (VOCs) - 500 pounds
Hydrogen Sulfide - 100 pounds
Cause of Problem: Human Factors

Personnel was making valve alignment changes when a block valve on the suction of the coker compressor was inadvertently closed. This caused the pressure to build in the overhead system until the pressure exceeded that of pressure vent set point. The pressure vents opened, resulting in overhead vapor to be released to the flare system, which resulted in the flaring of the hydrocarbon.
The RQ for SO2 was exceeded. The valve was reopened. Additional training and discussion was held for the personnel about the importance of valve misalignment. Company letter and State Police HAZMAT report differs on pollutant released.
No LDEQ Number Available

2009-05-11
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

There was a spill, but no further information provided about the cause.
The release of an unspecified material was BRQ. LABB only has access to the refinery letter.
114803

2009-05-11
Point Source(s):
No Information Given

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: No Information Given

According to the SPOC verbal report, a meter read a high SO2 concentration, but no information about what caused this high reading.
The RQ not exceeded, and there was a fluctuation in pressure for SO2. LABB does not have access to the LDEQ incident report.
114733

2009-05-07
Point Source(s):
bypass stack

Pollutant(s):
Nitrogen Oxide - 5,819 pounds
Flammable Vapor - 23,643 pounds
Sulfur Dioxide - 115,215 pounds
Cause of Problem: Equipment Failure

The Wet Gas Scrubber had a malfunction which led to failure of an expansion joining at CO Furnace, F-301. The malfunction required venting of PCLA 2 and 3 to bypass stacks and shutdown of Wet Gas Scrubber.
This incident exceeded RQs. PCLA-3 vented to bypass stack until shutdown was completed. All of the Wet Gas Scrubber nozzles were replaced. Root cause is under investigation.
114636

2009-05-01
Point Source(s):
No Information Given

Pollutant(s):
Hydrogen Sulfide - BRQ
Cause of Problem: Piping or Tubing

Leak occurred on pipe going to analyzer.
This release is BRQ.
114573

2009-04-30
Point Source(s):
No Information Given

Pollutant(s):
Volatile Organic Compounds (VOCs) - BRQ
Hexane - BRQ
Cyclohexane - BRQ
Benzene - BRQ
Xylene - BRQ
Toluene - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided regarding the cause.
RQ not exceeded. LABB does not have access to the LDEQ incident report.
114479

2009-04-27
Point Source(s):
FLARE

Pollutant(s):
Ethylene - BRQ
Propylene - BRQ
Sulfur Dioxide - BRQ
Hydrogen Sulfide - BRQ
Benzene - BRQ
Nitrogen Oxide - BRQ
Cause of Problem: Process Upset

Flaring occurred when compressor tripped off line.
RQ not exceeded. Restarted compressor. No LDEQ report or follow up.
114483

2009-04-26
Point Source(s):
safety valve on coker drum
safety vavle on coker drum

Pollutant(s):
Flammable Gas - BRQ
Hydrogen Sulfide - BRQ
Benzene - BRQ
Cause of Problem: Process Upset

Safety valve release on coker drum.
RQ not exceeded. Material rerouted to another drum.
114432

2009-04-24
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided regarding the cause.
The release of an unspecified material is BRQ. LABB only has access to the refinery report.
114324

2009-04-21
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information given regarding the cause.
The release of an unspecified material is BRQ. LABB only has access to the refinery report.
No LDEQ Number Available

2009-04-17
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

A Third Party Barge Leak occurred, but no information provided regarding the cause.
The release of an unspecified material was BRQ. LABB only has access to the refinery report.
No LDEQ Number Available

2009-04-16
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

A Third Party Barge Leak occurred, but no information provided regarding the cause.
The release of an unspecified material was BRQ. LABB only has access to the refinery report.
114187

2009-04-16
Point Source(s):
7&8 Separator

Pollutant(s):
Hazardous Waste - BRQ
Cause of Problem: Piping or Tubing

Water spilled out of a 7&8 separator due to a pinhole leak in the separator.
Release is BRQ.
114093

2009-04-13
Point Source(s):
Tk-192 mixer

Pollutant(s):
Oil - 88 pounds
Cause of Problem: Seal or Gasket

Leak from seal failure of Tk-192 mixer.
RQ exceeded. Contaminated soil removed. Shut-off shaft to stop leak. Mechanism of failure is under investigation.
114103

2009-04-11
Point Source(s):
GLA-3X compressor flare

Pollutant(s):
Sulfur Dioxide - 5,104 pounds
Propylene - 135 pounds
Cause of Problem: Instrument Failure

Level instrument of GLA-3X compressor was plugged which caused the reading to be erroneously high. Compressor tripped which caused pressure to build up and a flare to be emitted.
Release exceeded RQ. Unit rates decreased to stop flaring. Cause of compressor trip is under investigation. High level alarm is bypassed to prevent recurrence.
114092

2009-04-11
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided regarding cause.
The release of an unspecified material was BRQ. LABB only has access to refinery report.
114765

2009-04-11
Point Source(s):
No Information Given

Pollutant(s):
1,3-Butadiene - BRQ
Propylene - BRQ
Flammable Gas - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided regarding the cause.
Release is BRQ. LABB does not have access to the LDEQ incident report. The SPOC report indicates the release occurred on 05/07/09, but the refinery letter states the incident occurred on 04/11/09.
113891

2009-04-01
Point Source(s):
unspecified flare

Pollutant(s):
Sulfur Dioxide - 857 pounds
Cause of Problem: Equipment Failure

Flaring was caused by an overhead condenser leak at the PCLA complex. The overhead material at the PCLA fractionator is cooled using cooling tower water. A leak developed in these condensers which caused cooling tower water to enter the shell side of the overhead condensers. When the cooling tower water evaporated, salts and foulant were deposited in the process side of the overhead condensers, causing an increase in pressure drop. This increase in pressure drop caused the fractionator pressure to increase, and eventually exceed the set pressure of the pressure relief valves. The pressure relief valves released fractionator overhead into the flare gas recovery system, resulting in flaring. Sulfur Dioxide was released to the atmosphere in exceedance of the reportable quantity.
Unit pressure and unit feed rates were reduced to minimize overhead gas rates and eliminate flaring. Release exceeds RQ.
113842

2009-03-31
Point Source(s):
make-up hydrogen compressor (C-102B)

Pollutant(s):
Sulfur Dioxide - 978 pounds
Hydrogen Sulfide - 3 pounds
Nitrogen Oxide - 50
Nitrogen Dioxide - 8
Cause of Problem: Equipment Failure

Make-up hydrogen compressor (C-102B) malfunctioned which caused a higher rate of hydrogen into C-102 compressor. This increased pressure which resulted in a safety valve release and caused flaring.
Release exceeded SO2 RQ. The safety valve was removed from service. Pressure maintained by companion safety valve. Compressor will be repaired. Company report and State Police HAZMAT report differs on pollutants released.
113795

2009-03-30
Point Source(s):
No Information Given

Pollutant(s):
Flammable Gas - BRQ
Benzene - BRQ
Volatile Organic Compounds - BRQ
Cause of Problem: Process Upset

Safety valve lifted on tank. Pressure dropped.
RQ not exceeded.
No LDEQ Number Available

2009-03-30
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

No information provided regarding the release of an unspecified material.
RQ not exceeded. LABB only has access to refinery report.
113528

2009-03-20
Point Source(s):
701 tank manifold

Pollutant(s):
Xylene - 158 pounds
Oil - 281 pounds
Cause of Problem: Seal or Gasket

Flange leaking at 701 tanks manifold located at R and 20th. Flange not tightened properly. Reason for unaligned flange is under investigation.
RQ exceeded. Line evacuated and flange was realigned and tightened. Contaminated ground has been removed. New quality control application expected to come out of the investigation.
113502

2009-03-18
Point Source(s):
No Information Given

Pollutant(s):
Butane - BRQ
Cause of Problem: No Information Given

Absorber burped over and purged into the incinerator.
RQ not exceeded.
No LDEQ Number Available

2009-03-16
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided regarding the cause.
RQ not exceeded. LABB only has access to the refinery report.
113408

2009-03-15
Point Source(s):
#44 cooling tower

Pollutant(s):
Unknown Substance - BRQ
Cause of Problem: Equipment Failure

Leak in #44 cooling tower. Foaming occurred.
LABB only has access to the SPOC verbal report. No information provided about amount of material released, and the chemicals are unknown. There is a potential for VOCs released.
113150

2009-03-05
Point Source(s):
#20 flare

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: Process Upset

Flaring occurred at #20 flare.
RQ not exceeded.
113123

2009-03-04
Point Source(s):
No Information Given

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: Equipment Failure

According to SPOC verbal report, a leak occurred on CO furnace.
RQ not exceeded.
113059

2009-03-02
Point Source(s):
A and B exchanger on #4 depropanizer

Pollutant(s):
Propylene - 165 pounds
Xylene - BRQ
Benzene - BRQ
Toluene - BRQ
Cause of Problem: Corrosion

Hydrocarbon leak coming from one of two banks of exchangers of the #4 depropanizer. It is leaking from the shell side of the exchanger into the cooling tower water in the tube side of the exchanger. Leak was the result of unexpected corrosion of exchanger tubes.
RQ for propylene exceeded. Leaking exchangers isolated as soon as leak location determined. Tower was shut down and leaking tubes in overhead condensers were plugged to prevent further release.
113145

2009-02-28
Point Source(s):
No Information Given

Pollutant(s):
Hydrocarbon - BRQ
Cause of Problem: Piping or Tubing

According to the SPOC verbal report, a pinhole leak in a pipeline released nonliquefied hydrocarbon gas.
RQ not exceeded.
113020

2009-02-26
Point Source(s):
#100 tank

Pollutant(s):
Flammable Gas - BRQ
Cause of Problem: Process Upset

Pressure venting on tank #100 on vapor recovery system.
RQ not exceeded.
112927

2009-02-20
Point Source(s):
no information given

Pollutant(s):
Oil - BRQ
Cause of Problem: Piping or Tubing

A leak on the bottom of a suction line to a tank released oil.
Release is BRQ.
112910

2009-02-20
Point Source(s):
Bateman Lake Natural Gas header

Pollutant(s):
Carbon Dioxide - 53 pounds
Nitrogen - 33 pounds
Methane - 1,966 pounds
Ethane - 64 pounds
Cause of Problem: Human Factors

Technician working on pressure instrument did not notify unit operating controller. Malfunction caused pressure control valve to open, which caused the pressure in the Bateman Lake Natural Gas header to exceed that of safety vavle set point.
A total of 2030 pounds of flammable vapor was release which exceeds RQ. Pressure control valve was taken out of automatic control and placed into manual control.
112835

2009-02-17
Point Source(s):
Safety Valve

Pollutant(s):
Flammable Gas - 0 pounds
Cause of Problem: Process Upset

Safety valve release due to over-pressure.
Rates cut to relieve pressure. Release is BRQ.
112781

2009-02-16
Point Source(s):
No Information Given

Pollutant(s):
Volatile Organic Compounds (VOCs) - BRQ
Benzene - BRQ
Xylene - BRQ
Oil - BRQ
Unknown Substance - BRQ
Benzene - BRQ
Xylene - BRQ
Oil - BRQ
Unknown Substance - BRQ
Cause of Problem: Equipment Failure

According to the SPOC verbal report, a leak from the bottom of a tank caused the release.
Release is BRQ.
112755

2009-02-16
Point Source(s):
NIG

Pollutant(s):
Hydrogen Sulfide - BRQ
Benzene - BRQ
Cause of Problem: No Information Given

According to the SPOC verbal report, a leak to a cooling tower occurred, but no information provided about the cause. The source of the leak is still under investigation.
RQ not exceeded.
112758

2009-02-14
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information given regarding cause.
RQ not exceeded for an unspecified material. LABB only has access to the refinery report.
112756

2009-02-14
Point Source(s):
pipe to depropanizer tower on V-line

Pollutant(s):
Propylene - BRQ
Isobutane - BRQ
Cause of Problem: Piping or Tubing

According to the SPOC verbal report, a piping leak on the depropanizer tower on V-line caused a release.
Blocked line out to secure. Release is BRQ.
112696

2009-02-11
Point Source(s):
alky unit

Pollutant(s):
Isobutane - BRQ
Cause of Problem: Seal or Gasket

According to the SPOC verbal report, gas leaked in the Alky unit from a valve packing.
SPOC report indicates that as a result of this ongoing incident, an estimated 1,000 pounds/day of isobutane is being released. However the refinery letter reports that no RQs were exceeded. No information provided regarding when the incident was secured.
112619

2009-02-09
Point Source(s):
No Information Given

Pollutant(s):
Volatile Organic Compounds (VOCs) - BRQ
Cause of Problem: No Information Given

According to the SPOC report, there is a leak of VOCs into cooling tower water, but no information given regarding the cause. Source of the leak is unknown.
Exxon vacuumed the foam and minimized vaporization to the atmosphere. Release is BRQ.
112587

2009-02-08
Point Source(s):
No Information Given

Pollutant(s):
Sulfur Dioxide - BRQ
Cause of Problem: No Information Given

According to the SPOC verbal report, the sulfur dioxide 12 hour limit was exceeded and the incident is still under investigation. No information provided regarding the cause.
Under investigation. May be related to another unit that is in a turnaround. Release is BRQ.
112606

2009-02-08
Point Source(s):
Coker Feed Pump: P-6

Pollutant(s):
Polycyclic Aromatic Hydrocarbons - 4 pounds
Oil - 122 pounds
Naphthalene - BRQ
Cause of Problem: Piping or Tubing

Leak occurred because a stream of cold feed entered the suction of the pump. When the cold stream reached the pump, the pump began to cavitate, causing excess vibration. The vibration caused a line coming off of the pump to break.
The failed piping will be replaced with an upgraded class to withstand future upsets of this nature. Contaminated soil has been remediated and disposed of properly. The RQs for PAHs and oil to soil was exceeded.
112566

2009-02-06
Point Source(s):
atmospheric safety valve

Pollutant(s):
Flammable Vapor - 3,280 pounds
Cause of Problem: Instrument Failure

An atmospheric safety valve was lifted on the Opelousas Natural Gas header at Baton Rouge Refinery. the pressure of the header is maintained through a control valve, which opens to a lower pressure header. The control valve pressure instrument to the low pressure header failed in an open position, causing the pressure in the header to reach the release pressure of the safety valve.
Pressure instrument was replaced before returning to service. The RQ for flammable vapor was exceeded.
112551

2009-02-05
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: Seal or Gasket

According to the SPOC verbal report, a pipe flange leaked.
The release of an unspecified material was BRQ.
112424

2009-02-01
Point Source(s):
No Information Given

Pollutant(s):
Amylene - BRQ
Cause of Problem: Equipment Failure

According to the SPOC verbal report, after an internal odor complaint, a reboiler leak was discovered.
The leak is still under investigation. Release is BRQ.
112312

2009-01-27
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
The release of an unspecified material was BRQ. LABB only has access to the refinery report.
112275

2009-01-26
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
RQ not exceeded. No further information given. LABB only has access to the refinery report.
112161

2009-01-21
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred, but no information provided regarding the cause.
Release for unspecified material is BRQ. LABB only has access to the refinery report.
No LDEQ Number Available

2009-01-18
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
RQ not exceeded. No further information given.
112068

2009-01-15
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
RQ not exceeded. No further information given. LABB only has access to the refinery report.
112013

2009-01-14
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
RQ not exceeded. No further information given. LABB only has access to the refinery report.
111997

2009-01-13
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
RQ not exceeded. No further information given. LABB only has access to the refinery report.
111873

2009-01-08
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred- no further information given
RQ not exceeded. No further information given. LABB only has access to the refinery report.
111875

2009-01-07
Point Source(s):
pipe on Avenue F (between 7th and 8th Street)

Pollutant(s):
Oil - 311 pounds
Cause of Problem: Corrosion

Pipe on Avenue F between 7th and 8th Street was corroded. This led to a section of leaking pipe.
RQ exceeded. Leaking pipe was isolated and a temporary clamp was placed over the leak. The line will be permanently repaired. Vacuum trucks were used to collect material, and the contaminated soil is in the process of being removed. No groundwater impacts were expected.
112185

2009-01-02
Point Source(s):
No Information Given

Pollutant(s):
No Information Given - BRQ
Cause of Problem: No Information Given

Leak occurred. No further information given.
RQ not exceeded. No further information given. LABB only has access to the refinery report.
112184

2009-01-02
Point Source(s):
#17 flare and PCLA furnaces

Pollutant(s):
Sulfur Dioxide - 570 pounds
Cause of Problem: No Information Given

As a result of flaring at flare #17, 139 pounds of sulfur dioxide was released into the atmosphere. The SO2 release, in conjunction with the continuous SO2 release of 431 pounds/day from the PCLA Furnaces (State Police Number 08-07187), resulted in a release exceeding the RQ for SO2. No information given regarding the cause of these releases.
Combined release of SO2 from #17 flare and PCLA furances exceeded RQ. PCLA unit rates were reduced and critical overhead condensors were backwashed, and the PCLA furnaces were repaired during the unit turnaround scheduled for the first quarter of 2009.