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Marathon Ashland Petroleum (3165), Garyville

Releases of Pentene Plus

LDEQ Accident Number
Accident Date
Point Source(s) Notes Amount of Release
145377

2012-12-15
South Flare
Unit 59 South Flare
Cause: A tube leaked on the Unit 15 Hot Separator Overhead Fin Fans at 17:52 hours. At 18:00, the unit was undergoing emergency shutdown procedures and the U15 dump valve was opened to the flare. The incident was a Gas Oil leak in the Unit 15 Hot separator Overhead Fin Fan Exchangers. This leak caused a vapor release of hydrocarbons and hydrogen in addition to a small amount of hydrogen sulfide.

Followup: Yes

Notes: PDF was too large to upload. Unit 15 was depressurized to the South Flare to safely isolate the leaking Overhead Fin Fan. Once the unit pressure was sufficiently low in the unit, the Fin Fans were isolated and the leak stopped. An incident investigation will result in recommendations to prevent recurrence. The reportable quantities for hydrogen sulfide, compressed flammable gas, and compressed flammable liquid were exceeded during this event. A report on October 9, 2013, removed greenhouse gas emissions and revised the estimate of VOC emissions.
5,674.2 pounds
143781

2012-10-12

Unit 59 North Flare
Cause: The initiating incident was a pump seal fire in the Gasoline Desulfurization Unit (Unit 55). The fire was fueled by a leaking seal on the pump. Extinguishing the fire was delayed by inability to close an EIV on the suction side of the pump. This resulted in emergency shutdown of the unit. Two other events also occurred on this day including an upset in Sulfur Plant Unit 234 and a flame-out of the North Flare. Due to the fire and emergency shutdown of the Gasoline Desulfurization Unit, the Fluid Catalytic Cracking Unit cut feed, sending vent gas to the North Flare. Process vent gas was sent to the North Flare which increased the steam to the flare suddenly, snuffing the flare out.

Followup: Yes

Notes: PDF too large to upload (109 pages) To re-light the North Flare, steam was gradually decreased and natural gas was added to the flare gas to allow the two available igniters to relight the North Flare. Parts to repair the North Flare pilot system were already on order when this incident occurred. The North Flare was taken out of service when the parts were received and repaired on October 31, 2012. Spare pilot and igniter assemblies are now in stock so that repairs can be made in a timely fashion if an incident like this is to occur again. Total amount of pollutants released was 59438.44 lbs, but 90% was claimed to be efficiently burned off, resulting in 5943.59 lbs that were actually released. The reportable quantity for Highly Reactive Volatile Organic Compounds (HRVOCs) (100 pounds) was exceeded during the 24 hour period.
727.1 pounds
143319

2012-09-23
Emissions from Flare
emissions from flare and Unit 45 Thermal Oxidizer
Cause: Marathon experienced a partial power outage caused by a malfunctioning substation in the refinery resulted in multiple pieces of equipment in the refinery losing power. Low pressure stripper Offgas flared in the South Flare due to partial power outage. Enterprise incident due to a plant farther downstream that had uncharacteristically ceased operation due to an upset condition. The pressure safety valve, as designed, released discharging natural gas to atmosphere due to high pressure on the pipeline caused by the upset condition farther down the line. Emission points involved were the Unit 59 North Flare and the Unit 45 Thermal Oxidizer.

Followup: No

Notes: Marathon power was restored and the equipment that was shutdown was restarted to minimize further releases. An incident investigation will result in recommendation items designed to prevent the recurrence of this event. High sulfur dioxide from one of the thermal oxidizer stacks in Unit 45 and in addition to a small amount of Unit 15 low pressure stripper offgas was flared which contains a small amount of hydrogen sulfide which is converted to sulfur dioxide in the North Flare. Emission points involved were the Unit 59 North Flare and the Unit 45 Thermal Oxidizer. Enterprise personnel immediately began the process of taking the plant down in order to end the release event. Amount of natural gas released is above reportable quantity.
0.2 pounds
142430-142532

2012-08-28
flare
outfall 002
Cause: There were multiple units that experienced upsets during the shutdown and startup activities surrounding Hurricane Isaac: In preparation for Hurricane Isaac, the refinery units were at minimum rates anticipating a shutdown condition. As a result of these abnormal conditions, the refinery 150 PSIG steam header pressure was significantly low. The U205 Delayed Coker unit uses steam to purge resid and coke from the switch valve and ball valves on the coke drum structure. the low steam pressure ultimately led to the valve failing due to coke build up on the valve. On 8/28/2012 the unit was forced to go on bypass and internal circulation due to inability to switch feed to the offline drum. After the unit was on bypass the Wet Gas Compressor tripped three times. These trips resulted in releases to the flare. This resulted in a small amount of hydrocarbon material to be routed to the ground flare. Propane Flaring: Due to atypical operating conditions and the shutdown of our third-party propane pipeline, MPC flared propane starting on August 31 at 06:52 AM intermittently until September 1 at 02:45 AM. The flaring of propane was required to balance refinery operations. No reportable quantities were exceeded. The release calculations are provided in Attachment 4. North Stick Flare Flame Outage: On September 1, the North Stick Flare flame was snuffed out with steam for a total of five minutes. This occurred while decreasing the amount of propane flaring mentioned above. No reportable quantities were exceeded. This event was reported verbally on September 1st and a follow-up written report was submitted on September 7, 2012 (see Attachment 5). North Stick Flare Damage: The North Stick Flare was observed to have some abnormal flame patterns prior to Hurricane Isaac. However, during the hurricane it was noticed that one side of the flare tip had more significant flames. After the hurricane on September 11 th an inspection, via a remote helicopter, observed that a natural gas supply line to the pilots had a broken union. This was causing natural gas to burn just below the flare tip. It is believed that the high winds experienced during the hurricane caused the union to completely break apart. A repair plan is being formulated to correct this issue. Wastewater Discharge: MPC discharged untreated process area stormwater via Outfall 002 to the Lake Maurepas drainage system beginning on August 30, 2012 at 07:00 hrs intermittently until September 3, 2012 at 13:00 hrs. The amount of wastewater discharged is estimated to be 300,000 bbls (which is 12,600,000 gallons). Samples were collected prior to the discharge and after the start of discharge to verify that the water being discharged was sufficient quality to ensure no harm to environment. The discharge was monitored to ensure that there was no sheen on the water discharged off-site. It should be noted that prior to discharging the untreated process area stormwater, MPC had reached the on-site WWTP storage capacity of 619,995 bbls of water. In addition, MPC placed an out of service crude oil tank (500-2) back into service prior to the hurricane specifically to be used for wastewater and slop oil storage as needed. This tank was used for excess water storage prior to any wastewater being discharged off-site.

Followup: No

Notes: This report is linked to two LDEQ incident numbers: 142430 and 142532. Unit 205 Coker sent to the North Ground Flare. The release was identified at approximately 06:35 hours on August 29. 2012 and lasted for approximately 1944 minutes (1d 8h 24m). The compound of concern was Propylene. Totals of 76.54 lbs and 86.15 lbs were released during the 2 24-hour periods involved. MPC considers these emissions to be covered under the temporary variance issued on August 27 of 2012. That variance authorized the temporary permit for the emissions: Sulfur Dioxide 13.3 tons; Nitrogen Oxide 0.9 tons; Carbon Monoxide 7.03 tons; Volatile Organic Compounds (VOCs) 8.51 tons; Hydrogen Sulfide 0.73 tons. There was also a variance for 3,750 long tons(8,400,000lbs) of sulfur to be stored on a "sulfur pad". These variances were considered the maximum allowed during that period, therefore they are not included in LABB pollutant totals in this report. As soon as conditions allowed, the compressor was restarted. Missed Monitoring/Repair/Inspections Due to the hurricane, personnel were not available to complete several regulatory required tasks, such as weekly inspections, PMs, monitoring, and repairs. The programs and the specific missed requirements are listed below: LDAR Program 5-day first attempt at repair requirement (five components) 15-day final repair requirement (twelve components) Waste Program Weekly satellite collection area inspection (two locations) Weekly hazardous waste storage area inspection Weekly non-hazardous waste storage area inspection Weekly universal waste area inspection Weekly used oil storage area inspection Stormwater Pollution Prevention Program Weekly refinery inspection Spill Prevention Control & Countermeasures Program Weekly inspection of the Contractor Village area MACT II - NSPS Subpart UUU Weekly PM for the pH meter used for compliance demonstration Benzene Waste Operation NESHAP Carbon Canister monitoring for breakthrough (eight events) 15-day repair requirement (four sumps) There is a separate report on this database for the sinking of the "Big Tuna" response boat. Response Boat Fuel Loss: The oil spill response boat became submerged in the Mississippi River on August 29th, due to a surge in the river level which resulted in the loss of ten gallons of gasoline. The reportable quantity for oil was exceeded. This event was reported verbally on August 31 and a written follow-up report was submitted on September 7, 2012 (See Attachment 3). (Attachment 3 was deleted from this file, and added to the report for this event)
81.6 pounds
No LDEQ Reported

2013-07-24
Unit 250 North Ground Flare
Cause: On July 24, 2013, the Unit 210 Crude Overhead Compressor shut down at 16:11 hours and was restarted at 16:26 hours. A second shutdown occurred at 16:48 hours and was restarted at 17:02 hours. A third shutdown occurred at 17:25 hours and was re-started at 17:56 hours. The duration of Unit 210 venting to the North Ground Flare was 60 minutes. Approximately 613 pounds of sulfur dioxide were released (over the reportable quantity of 500 pounds).

Followup: No

Notes: Liquid was drained from the Unit 210 Compressor Suction Drum. The Unit 210 Crude Overhead Compressor was re-started. A very similar event occurred on March 25, 2013 with emissions from the same point source. This report retrieved from EDMS was labeled with the LDEQ number corresponding to the March 25, 2013 incident (LDEQ # 147603). The March 25th event also involved multiple shutdowns of the Unit 210 Crude Overhead Compressor, and the report labeled that event as preventable. It is interesting to note that a similar event labeled preventable occurred less than four months later.
101.2 pounds
149432

2013-06-29
leak from process line in U263 piperack
Cause: On June 29, a pinhole leak was discovered in the LPG feedline from U212 to U222.

Followup: No

Notes: The line was purged with nitrogen and isolated for repairs. The Shift Emergency Response Team was activated and fire monitors were put on the leak to suppress any vapors. Reduced the U212 charge rate to minimize the leak. The line was isolated at battery limits in U222 and U212 to stop the leak. Once the investigation is complete, recommendations will be implemented.
3.5 pounds
148876

2013-05-22
U212 Platformer unit
Cause: On May 22, a small leak and hydrogen fire was observed on the 48" flange on the process piping going from cell 1 of the Unit 212 Charge Heater to Reactor #1. The leak was pinhole sized in width and no larger than 1" around the circumference of the flange. The emission point involved was a flange on a process line in the U212 Platformer unit.

Followup: Yes

Notes: Steam was applied to the flange to extinguish the flame and the flange was hot bolted to secure the leak. Once the investigation is complete, recommendations will be implemented. An additional followup on 10/23/13 corrected the initial followup report's emissions data regarding greenhouse gas releases.
0.3 pounds
148807

2013-05-19
Flow indicator 15FI0214
Cause: On May 19, the impulse lines on flow indicator 15FI0214 pulled away from the root valve. Blow taps on the valve blew off and released make-up hydrogen to the atmosphere. The causal factors leading to the failure of the tubing was Equipment Difficulty/Design Specs/Problem Not Anticipated. There were issues with the metallurgy of the tubing and the elevation of the transmitter in relation to the orifice taps.

Followup: Yes

Notes: Water from the fire monitors was sprayed on the release to help disperse the gas and prevent ignition. The board operator began depressurizing the unit through the dump valve in preparation for emergency shutdown. The line was isolated from the rest of the process unit to prevent further release of make-up hydrogen. To prevent recurrence, the following recommendations were made: 1) relocate the transmitter above the orifice taps on 15FE0214, and 2) replace stainless steel components of 15FT0214, including the impulse tubing with Hastelloy to prevent chloride-induced stress corrosion cracking. Also to tag the instrument tubing to indicate that the material is Hastelloy. Approximately 6.214 pounds of compressed flammable gas and 28 pounds of hydrogen sulfide were released.
556.6 pounds
147603

2013-03-25
Unit 259 North Ground Flare
Cause: The two root causes identified were the benzene stripper lower level controller malfunctioned and the operator did not have sufficient response time. On March 25, 2013 the Unit 210 Crude Overhead Compressor shut down at 18:03 hours and was restarted at 18:26 hours. A second shutdown occurred at 19:23 hours and was re-started at 19:41 hours. The duration of Unit 210 venting to the North Ground Flare was 40 minutes. Approximately 3,385 pounds of sulfur dioxide were released (above the reportable quantity of 500 pounds). On March 25, 2013 at 17:45 hours, issues developed in the Unit 210 Desalter vessels. As a result of the event, liquid was carried over from the Desalters to downstream Unit 210 vessels. Eventually, liquid filled the Unit 210 Overhead Compressor Feed Knockout drum which shut down the Overhead Compressor. The ambient air monitoring stations located by the ground flares did not detect a significant increase in sulfur dioxide emissions.

Followup: Yes

Notes: Liquid was drained from the Unit 210 Crude Overhead Compressor Feed Knockout Drum. The Unit 210 Crude Overhead Compressor was re-started. While sulfur dioxide was the only chemical released above reportable quantity, NOx, monoxide, VOCs, PM10, PM2.5,HRVOCs, and hydrogen sulfide were released over the permit limit. An accident investigation was conducted to determine the cause(s) of the incident. The two root causes identified were 1. Equipment difficulty, design, problem not anticipated (Benzene stripper lower level controller malfunctioned); and 2. human engineering, non-fault tolerant system, errors not recoverable (operator did not have sufficient response time). The following recommendations will be implemented: 1. redesign or upgrade the benzene stripper level indicator 210L10197 to provide backup level indication for 210LC0187 due 12/20/13; 2. add soft stops to 210L1097 to limit flow from the 1st stage Desalter to the Benzene Stripper- complete; and 3. evaluate the hydraulics of the Benzene Stripper bottoms circuit and consider developing a project to eliminate constraints in the system- due 12/20/13.
1.7 pounds
146849

2013-02-21
Unit 259 South Ground Flare and Unit 259 North Ground Flare
Cause: The Unit 214 Kerosene Hydrotreater experienced an emergency shutdown at 16:18 hours on February 21, 2013. The process unit vented to the South Ground Flare for 94 minutes. The Unit 210 Crude Overhead Compressor shutdown at 16:39 hours on February 21, 2013 was re-started at 16:58 hours on February 21, 2013. The duration of Unit 210 venting to the North Ground Flare was 19 minutes. On February 21, 2013, at 16:18 hours, a power failure caused the Unit 214 Kerosene Hydrotreater to experience an emergency shutdown. As a result of the event, liquid was carried over from Unit 214 to the Unit 210 Crude Overhead Compressor system. The liquid filled the Unit 210 Overhead Compressor Feed Knockout drum which shut down the Overhead Compressor. The ambient air monitoring stations located by the ground flares did not detect a significant increase in sulfur dioxide emissions. The main parts of this accident were the emergency shutdown of the 214 Kerosene Hydrotreater and flaring from the Unit 210 Crude Overhead Compressor. The causal factor for the Unit 214 Power Failure and subsequent emergency shutdown was determined to be Equipment Difficulty/Tolerable Failure. The Causal factor for the Unit 210 flaring event was determined to be Human Performance Difficulty/Management System/SPAC Not Used/Enforcement Needs Improvement.

Followup: Yes

Notes: Power was restored to the Unit 214 Kerosene Hydrotreater and the unit was re-started. Liquid was drained from the Unit 210 Crude Overhead Compressor Feed Knockout Drum. The Unit 210 Crude Overhead Compressor was re-started. An incident investigation will result in recommendation items designed to prevent the recurrence of this event. In the 60 day follow up report dated 4/22/13, the following remedial actions were listed in response to the release: Unit 214 portion of the upset: 1) Maintenance corrective actions immediately following release. Electricians and instrument Techs responded to the Satellite building. Power panel 214-PP-B01 main breaker and substation 214-MCC-B01 were reset establishing power to the first power supply. 214-HVAC-B008 was repaired and brought back online. 2) Operations corrective actions after the release. Unit 214 board operator started procedures for shutting down unit. Unit 214 valves 214FC0007 (Heavy Coker Naptha Feed Valve) and 214FC0006 (Kerosene from tankage valve) were closed 15 minutes after the start of the release. Operations awaited Maintenance's confimation that the unit was ready to restart. Unit 210 portion of the upset: 1) Unit 210 operators followed the event reponse matrix to verify the compressor suction drum (210-1202) level, the compressor suction drum valve position, and whether or not the suction drum pumps were running. Operations than began working to get the level down in the suction drum in preparation for restarting the OFFGAS compressors. For the Unit 214 portion of the incident the following recommendations were made: 1) Update the Marathon Standard Practice to require a cicuit breaker cooridination study for all 480V power panel installations for future projects - due 12/31/13; and 2) Evaluate the cicuit breaker coordination for all existing 480V power panels throughout the refinery and determine necessary solutions to achieve coordination where required - due 8/30/14 3) For the Unit 210 portion of the incident the following recommendation was made: Review and Reinforce the Emergency Shutdown Procedures for Unit 214 with the Board Operators - complete. An additional followup on 10/23/13 corrected the initial followup report's emissions data regarding greenhouse gas releases.
3.9 pounds
146138

2013-01-17
Unit 259 North Ground Flare
Cause: Unit 222 Sats Gas Plant experienced an upset due to an over-pressure condition on the debutanizer column. As a result, pressure relief valves lifted, sending debutanizer overhead material to the refinery's North Ground Flare. Root cause was a faulty pressure transmitter.

Followup: No

Notes: The Board Operator decreased pressure on the debutanizer column. The faulty transmitter was replaced. Initial reports from January, 2013 stated no permit limits were exceeded concerning released pollutants. Final calculations from April 4, 2013 determined otherwise.
46.0 pounds
157090

2014-06-27
Unit 25 FCCU wet gas compressor shutdown
Cause: The wet gas compressor (WGC) suction flow and discharge pressure dropped suddenly, causing the WGC spillback valve to open 100%. The fractionator overhead pressure increased when the WGC spillback opened up. The high fractionator pressure SIS trip point was reached (36 psi), which tripped the unit. Fuel gas was routed to the fractionator overhead accumulator, which was being vented to the flare to keep pressure on the reactor to prevent O2 from the regen from backing into the reactor. No offsite impacts were observed by the air monitoring team. The reportable quantities for Sulfur Dioxide, HRVOCs and VOCs were exceeded. Update: cooling coil in Alkyl Unit Vent Gas Absorber (27-1107) failed.

Followup: Yes

Notes: The SIS system reacted as designed to shutdown the FCCU due to the opening of the compressor spillback valve. An incident investigation will result in recommendation items designed to prevent recurrence of this event. Update: The root causes were identified as 1) cooling coil in Alkyl Unit Vent Gas Absorber (27-1107) failed. Cause of failure is unknown. Root Cause #1: Cannot be determined until the Alkyl Unit Shutdown. Recommendation: Inspect the cooling coil in the Alkyl Unit Vent Gas Absorber (27-1107) and determine cause of failure. Based on the cause of failure, recommendations will be generated to prevent recurrence. [Complete by December 15, 2016] 2) Quaterly PMs on cooling coil in Alkyl Vent Gas Absorber failed to identify the coil was leaking. Root Cause #1: No Procedure. Recommendations: Create Operations procedure for performing the quarterly leak testing on the cooling coil in the alkyl Vent Gas Absorber. Include a step that requires operators to verify proper documentation of test result in PM work order closure. [Complete by November 18, 2014]. Root Cause #2 Preventive/Predictive Maintenance Needs Improvement. Indetify flouride sample locations for discovering a leak in Alkyl Vent Gas Absorber cooling coil [Complete by November 18, 2014].
719.8 pounds
157090

2014-06-27
Unit 25 FCCU wet gas compressor shutdown
Cause: The wet gas compressor (WGC) suction flow and discharge pressure dropped suddenly, causing the WGC spillback valve to open 100%. The fractionator overhead pressure increased when the WGC spillback opened up. The high fractionator pressure SIS trip point was reached (36 psi), which tripped the unit. Fuel gas was routed to the fractionator overhead accumulator, which was being vented to the flare to keep pressure on the reactor to prevent O2 from the regen from backing into the reactor. No offsite impacts were observed by the air monitoring team. The reportable quantities for Sulfur Dioxide, HRVOCs and VOCs were exceeded. Update: cooling coil in Alkyl Unit Vent Gas Absorber (27-1107) failed.

Followup: Yes

Notes: The SIS system reacted as designed to shutdown the FCCU due to the opening of the compressor spillback valve. An incident investigation will result in recommendation items designed to prevent recurrence of this event. Update: The root causes were identified as 1) cooling coil in Alkyl Unit Vent Gas Absorber (27-1107) failed. Cause of failure is unknown. Root Cause #1: Cannot be determined until the Alkyl Unit Shutdown. Recommendation: Inspect the cooling coil in the Alkyl Unit Vent Gas Absorber (27-1107) and determine cause of failure. Based on the cause of failure, recommendations will be generated to prevent recurrence. [Complete by December 15, 2016] 2) Quaterly PMs on cooling coil in Alkyl Vent Gas Absorber failed to identify the coil was leaking. Root Cause #1: No Procedure. Recommendations: Create Operations procedure for performing the quarterly leak testing on the cooling coil in the alkyl Vent Gas Absorber. Include a step that requires operators to verify proper documentation of test result in PM work order closure. [Complete by November 18, 2014]. Root Cause #2 Preventive/Predictive Maintenance Needs Improvement. Indetify flouride sample locations for discovering a leak in Alkyl Vent Gas Absorber cooling coil [Complete by November 18, 2014].
719.8 pounds
15660

2014-06-07
FCCU wet gas compressor first stage
Cause: A loose wire in a satellite building caused the Fluid Catalytic Cracking Unit (FCCU) wet gas compressor first stage spillback to open, which led to high fractionator pressure. The safety instrumented system (SIS) tripped the FCC unit on high fractionator pressure. During the FCC unit startup, the debutanizer pressured up and had to be vented to flare due to lack of heat in the upstream stripper reboiler (heating medium is BPA from the fractionator) which sent ethane to the debutanizer. The flaring event due to the FCCU Shutdown began on June 7, 2014 at 14:37 hours and stopped on June 7, 2014 at 15.48 hours for a duration of 70 minutes. The flare event due to the FCCU startup began on June 7, 2014 at 18:21 hours and stopped on June 7, 2014 at 20:18 hours for a duration of 117 minutes. The total duration of the flaring was 187 minutes.

Followup: No

Notes: The SIS system reacted as designed to shutdown the FCCU due to the opening of the compressor spillback valve. During FCCU startup the operating procedure was followed to minimize emissions to the extent possible. An incident investigation will result in recommendation items designed to prevent the recurrence of this event.
22.1 pounds
153584

2014-01-27
Unit 59 North Flare (EQT#0162)
Cause: During propylene truck offloading activities, truck rack personnel began the normal Unit 65 process by opening a line to the flare to begin the transfer process. The line should be closed after the transfer to storage begins. However, the Unit 65 personnel failed to close the flare line and an amount of material went to the flare instead of to storage.

Followup: No

Notes: Upon discovery, the line that was open to the flare was closed and the procedure was reviewed with the operator to prevent reoccurrence.
0.9 pounds