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CITGO Petroleum (1250), Lake Charles

Releases of Sulfur Dioxide

LDEQ Accident Number
Accident Date
Point Source(s) Notes Amount of Release
84791

2005-12-23
B-Topper Unit
B-7 Flare
Cause: Piping leak at the B-Topper Unit. Due to the temperature of the naphtha steam and the elevation of the line relative to the ground, the leaking material evaporated and did not reach the ground.

Followup: Yes

Notes: Original letter states that the phone call to report this incident occurred on December 24, 2005, while the follow up letter states the incident occurred on December 23, 2005 at 23:45 hours. Claims all pollutants were released as liquids but vaporized before reaching the ground. Heavy naphtha release was below reportable quantities. The pumparound piping from which the leak was coming was shutdown and isolated for repair when the Unit was shutdown. A Failure Analysis was scheduled for this incident. Second attached letter states that upon re-start up of the B-Unit Topper on December 29, H2S and SO2 were possibly released but below reportable quantities
84711

2005-12-20
Sulfuric Acid Plant
Cause: Possible release of H2S and SO2 during a routine startup of the Sulfuric Acid Plant.

Followup: No

Notes: Claims emission was below RQ.
84652

2005-12-17
B-11 FLARE
Cause: Result of a shutdown of the JC-201 Compressor at the Coker II Unit. Root cause was due to an incorrect engineering design flaw in Transformer 444-S49-TRI-A protective relaying scheme. Transformer had been taken out of service to repair a secondary busing oil leak, and during re-energizing of the transformer the malfunction caused a power outage, causing shutdown on several critical pumparound pumps; the resulting loss of heat removal caused the overheated drum F-210 to fill with liquid.

Followup: Yes

Notes: Caused the 4.16kV tie breaker to open when the differential relay operated. A significant contributing cause of the additional flaring after power was restored was the plugging of the case drains on JC 210 compressor. Engineering calculations states that they expected SO2 released to be slightly lower than their original report, under the NRS Consent Decree, and then stating that they calculated 35,458 lbs were released. No information given on amounts of H2S or CO2 released (does not say specifically BRQ, but only SO2 was listed as exceeded permit levels).
35,600.0 pounds
83653

2005-11-03
B-11 flare
Cause: Release coming from a B-11 on-site flare, routine shutdown of the Unicrackert Unit

Followup:

Notes: Claims emission was below RQ. Handwritten note states 'Update to rits05-3566 T82492'. No official time of when release was stopped, but LDEQ notes that the incident was 'secured' on November 7 at 10:00 AM when the system returned on line.
82874

2005-10-06
FLARE
Cause: Plant startup after Hurricane Rita possible release of H2S and SO2.

Followup: No

Notes: No information given
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
1,161.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
23,441.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
2,689.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
1,007.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
8,710.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
579.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
1,015.0 pounds
82492

2005-09-22
Unicracker; C-FCCU
Unicracker; C-FCCU; B-5 FLARE; B6 FLARE; B7 FLARE
Multiple Units
B-5 FLARE; B6 FLARE; B7 FLARE
CLAW sewer
B 104 FLARE
A Topper; B Topper; Coker II; C FCCU
Coker I, C Sulfur Recovery Unit; B Sour Water Stripper
Tank 504
E Sulfur Recovery
A Sulfur recovery Unit; B Sour Water Stripper; Unicracker
Unicracker
Unicracker; D Sulfur Recovery Unit
Cause: Shut down and start up from Hurrican Rita

Followup: Yes

Notes: Summary of releases over 31 days
6,300.0 pounds
82213

2005-09-14
B-12 Flare
Cause: Routine shutdown of the Unicrackert Unit.

Followup: No

Notes: States no offsite impact.
4,853.0 pounds
82155

2005-09-13
No Information Given
Cause: First report letter states cause as routine shutdown/startup of the Sulfuric Acid Plant, and that no RQs were exceeded. Second letter for the same incident date claims the release was the result of a small hole found in the shell of the B-502 Reaction Furnace at the D-Sulfur Recovery Unit, and still stating that no RQs were exceeded. Third letter reiterates that it was a routine shutdown, but that RQs may have been exceeded.

Followup: No

Notes: Claims emission was below RQ in first two letters. All different dates for times of phone call notification (September 12, 13, and 14) and all assigned different case numbers.
82129

2005-09-12
B-502 reaction furnace
Cause: Small hole in shell of B-502 Reaction Furnace at D-Sulfur Recovery Unit.

Followup: No

Notes: Claims emission was below RQ, but also unknown rate of release although hole is very small. Will fabricate a pad to weld over leak.
81597

2005-08-23
B-12 FLARE
Cause: Outage of JC-1B recycle Hydrogen Compressor at Unicracker Unit.

Followup: No

Notes: Claims emission was below RQ
81431

2005-08-17
B-7 FLARE
Cause: Unexpected shutdown of JC-36 Compressor at the B-Topper Unit.

Followup: No

Notes: Claims emission was below RQ
81125

2005-08-11
Sulfuric acid Plant
Cause: Routine start up of Sulfuric Acid Plant.

Followup: No

Notes: Claims emission was below RQ
81175

2005-08-10
FLARE - B-12 Unicracker
Cause: Overpressure of the E101 tower and a PSV relieved pressure to the flare - root cause of the upset was an incorrect and unresponsive transmitter on pressure controller

Followup: Yes

Notes: Reduced pressure for the pressure safety valve to reseat. RCFA underway. No offsite impact.
1,077.0 pounds
80604

2005-07-25
B-12 Flare
Cause: flaring of excess hydrogen during outage of JC-1B recycl Hydrogen Compressor at Unicracker Unit

Followup: No

Notes: Claims emission was below RQ. Shut unit down and repaired compressor
80676

2005-07-22
Coker Unit #1
Cause: Coker Unit caught fire when resideual product was being put into the drum

Followup: No

Notes: Claims emission was below RQ. The level detectos on the coker drums detected small amount of radiation. Flexible hose rupture on F-201A coke drum silicon injection system.
10,951.0 pounds
80714

2005-07-22
Sulfuric acid Plant
Cause: routine start up of Sulfuric Acid Plant

Followup: No

Notes: Claims emission was below RQ
80493

2005-07-13
B-7 Flare
Cause: shutdown for planned maintenance of the B-Topper Unit

Followup: No

Notes: Claims emission was below RQ
79736

2005-06-10
Sulfuric acid Plant
Cause: routine start up of Sulfuric Acid Plant

Followup: No

Notes: Claims emission was below RQ
79333

2005-06-01
B-12 FLARE
Cause: the console operator put the F-1 feed drum pressure controller PC-003 in the manual closed position and failed to put it back in automatic

Followup: No

Notes: The Filter Maintenance Inspection Preparation Procedure will be revised to address a standard method for console operators. A Hard alarm will be installed for PSL 009.
4,983.0 pounds
79366

2005-05-25
B-12 FLARE
Cause: unexpected short time loss of the Recycle Hydrogen Compressor JC-1B during start up of the Unicracker Unit

Followup: Yes

Notes: Claims emission was below RQ
79154

2005-05-17
B-11 FLARE
Cause: -Flaring of Coker II Fractionator Overhead Gas from upset of E201 Tower

Followup: Yes

Notes: Facility failed to comply with control equipment regualtion - any deveice, operating procedure or abatement scheme used to prevent or reduce air pollution. The valve should not have allowed water to infiltrate the coke drum. Will revise operating procedures, train operators on trouble shooting skills; and install a flow indicato
6,800.0 pounds
78602

2005-04-28
B-5 FLARE
Cause: during shutdown for planned turnaround of C-Topper and Straight Run Fractionation Units

Followup: No

Notes: Claims emission was below RQ. State police state that flaring will go on for 24 hours.
77796

2005-03-23
FLARE Vacuum 2 Unit CLAW
Cause:

Followup: No

Notes: Claims emission was below RQ. Flaring of vacuum sump gas. The LC 103 Control Valve caught on fire at the packing. Material going through valve was 325 Oil and was so hot started fire. Went to flare while shutting down.
77616

2005-03-15
B-101 Furnace Coker I Unit
Cause: furnace fire caused by a tube rupture

Followup: No

Notes: Heater box fire put out by steam. Claims that no RQs were exceeded
77263

2005-03-02
Process furnaces
Cause: facility failed to have pump motors that possessed ground faults

Followup: Yes

Notes: A new motor for the pump that had the ground fault is on order
30,266.0 pounds
77213

2005-03-01
B-6 Flare
Cause: debutaizer Tower at the Straight Run Fractionation Unit

Followup: No

Notes: Claims emission was below RQ
77237

2005-02-26
No Information Given
Cause: B Topper upset

Followup: No Information Provided

Notes: CITGO failed to provide a written report. Investigation pending by DEQ letter dated 8/26/06
77217

2005-02-26
B-7 Flare
Cause: The guideline for managing high BS&W crude was not followed by the Product Inspector

Followup: Yes

Notes: Instituted a crude dewatering plan. Drafted a formal written procedure re: clear commuication and plan of action prior to pumping crude oil in takage to an operating unit. Train personnel on crude BS&W specifications. referred for enfrocement action from LDEQ
1,397.0 pounds
77022

2005-02-17
C-Fluid Catalytic Cracking Unit
Cause: exchanger fire

Followup: No

Notes: Claims emission was below RQ. Verbal report mentions slurry oil and fire due to small leak on the C-105 exchanger.
76995

2005-02-17
Water cooler at Sulfuric Acid Plant
Cause:

Followup: No

Notes: Claims emission was below RQ. Water leak containing SO2
76700

2005-02-03
B-12 Flare
Cause: valve packing failure in the high pressure reactor section of the Unicracker Unit during start up of planned shutdown

Followup: No

Notes: 2006 Inspection report from DEQ - locking nuts used to hold the valve in place were not suitable for service and were replaced
2,187.0 pounds
75706

2005-01-25
B-12 Flare
Cause: Unicracker Unit was shutdown for repairs. Emissions occurred during repeated start up; - failure of seal on JP127 propane transfer pump significantly contributed to SO2 H2S emissions

Followup: No

Notes: Failure of propane transfer pump seal contributed to 12.300 pounds of SO@ and all of the H2S emissions.Incident recurring since 12/27/04. Performing RCFA to be completed.
23,089.0 pounds
76431

2005-01-25
B-7 Flare
Cause: unexpected shutdown of JC-2D Wet Gas Compressor at the A Fluid Catalytic Cracking Unit

Followup: No

Notes: Claims emission was below RQ
76257

2005-01-19
B-7 Flare
Cause: unexpected shutdown of JC-2D Wet Gas Compressor at the A Fluid Catalytic Cracking Unit

Followup: No

Notes: Claims emission was below RQ
76256

2005-01-15
B-7 Flare
Cause: flaring of Topper Tail Gas from an eunexpected shutdown of the JC-36 Compressor at the B Topper Unit

Followup: No

Notes: Claims emission was below RQ
76011

2005-01-06
Sulfuric acid Plant
Cause: of sulfuric acid plant

Followup: No

Notes: Claims emission was below RQ
92895

2006-12-27
D-Sulfur Recovery unit
Cause: start up of the D-Sulfur Recovery Unit from a planned turnaround

Followup: No

Notes: Claims emission was below RQ
92861

2006-12-27
Unicracker Unit
Cause: Leak on a split tee connection on a stopple on the E-1 Debutanizer Tower reflux line that caused the shutdown of Unicracker Unit

Followup: No

Notes: Claims emission was below RQ
92761

2006-12-19
B-11 Flare
Cause: loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: Claims emission was below RQ
92251

2006-11-26
B-5 Flare
Cause: upset of the E1 Tower at the C-Topper Unit

Followup: No

Notes: Claims emission was below RQ
92237

2006-11-22
Thermal oxidizer
Cause:

Followup: No

Notes: 5th Lake Charles tail gas incident in the past 12 mo.sÉp.1 The current equipmt design of the C-SRP is not adequate to meet the New Source Review Consent Decree of 500 lbs SO2.; p. 4 Remedy A: Implement the low emission start-up recommendations in Option 1 of the C-SRU Tail Gas Alternate Disposition Project Study / Remedy B: Ensure that expert qualified SRU/TG analyzer technicians are scheduled for the duration of a planned Unit start-up
2,400.0 pounds
91874

2006-11-05
Flare - unplanned shutdowns of 3 catalytic cracking units, 2 reformers, 2 hydrotreaters and a fractionation unit, 4 satellite amine contactors
Cause: occurred in the power feeder cable due to upstream electrical equipment malfunction/substation malfunction

Followup: Yes

Notes: Sulfur Dioxide reported emissions is 34,339 ABOVE PERMITTED LIMIT which is not stated. Claims other emissions are below RQ. Formal Root Cause analysis to be done within 45 days of incide
34,339.0 pounds
06-BB006-941

2006-11-04
No Information Given
Cause: routine startup of Sulfuric Acid plant

Followup: No

Notes: No Information Given
91428

2006-10-17
B-104 Furnace in the B-Topper Unit
Cause: furnace tube leak

Followup: No

Notes: Claims emission was below RQ
91022

2006-10-01
No Information Given
Cause: No Information Given

Followup: No

Notes: No Information Given
90890

2006-09-26
B-11 Flare
Cause: loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: No Information Given
90424

2006-09-03
B-Catalytic Gasoline Hydrotreater
Cause: JP 204B stripper bottoms pump on the E 201 Interstage Stripper Tower experienced a seal failure. Due to the compostion and operating conditions and location within the unit, the Hydrocarbons released auto-ignite

Followup: No

Notes: No Information Given
88861 & 88862

2006-06-25
CLAW
Cause: level controller malfcuntion st the Lube Vacuum Unit 1

Followup: No

Notes: Claims emission was below RQ
88679

2006-06-19
B-12 flare, wastewater treatment plant
Cause: Refinery experienced a heavy rainfall event, greater than 8 inches;of rain in 36 hours. 250 psig steam lines became submerged in water and as a result the steam condensed and caused a drop in pressure, eventually stopping the flow of rich amine throughthe Central Amine unit. This resulted in the loss of acid gas production. The SROs eventually shutdown due to lack of feed. Off gas went to the B-12 flare. Rainfall runoff exceeded the available capacity of the wastewater treatment system storm water tanks and the treatment system. When the capacity of the storm water tanks was exceeded, slop oil and wastewater overflowed from the tanks into the protective dike area surrounding the tanks allowing evaporation of benzene, etc.

Followup: Yes

Notes: The lack of amine treatment of refinery fuel gas caused the hydrogen sulfide content in fuel gas to exceed permit limits Hydrogen Sulfide amounts exceeded not reportedÉTo increase the pressure of the steam system and to reuce hydrogen sulfide generation, emergency steam and hydrogen sulfide shedding steps were initiated. Several units feed rates were reduced to minimum and some were shut down. As soon as acid gas was available steps were taken to restart the SRUs. For each restart operations pnnel followed standard operations procedures for startup and shutdown. When the storm water tanks began to overflow, steps were taken to remove slop oil from the tank dike using vacuum dikes. The feed rte of wastewater from the wastewater tanks to
203,217.0 pounds
84957

2006-01-04
FLARE - B 12 Flare and Furnace Flange fire at the Unicracker Unit
Cause: caused the shut down of the Unicracker Unit and during restart there were emissions

Followup: No

Notes: Since the reactor section of the Unicracker Unit was shutdown as the result of this incident, will use same case number in any notifications regarding reportable emissions from the restart of the Unicracker Unit. CITGO is evaluating a project to route the non-condensable gas to a compressor on anoher unit for recovery and treatment. If the project is approved,it will be installed at the Unit's next scheduled turnaround.
3,881.0 pounds
101791

2007-12-18
Sulfuric Acid Plant
Cause: start up of Sulfuric Acid Pla

Followup: No

Notes: CITGO letter states that no RQ's were exceeded
101736

2007-12-16
B-7 Flare
Cause: see notes

Followup: No

Notes: High second stage discharge temperature trip of the JC-36 topper tail gas compressor
101728

2007-12-14
Thermal Oxidizer
Cause: start up of D- Sulfur Recovery Unit (D-SR

Followup: No

Notes: CITGO letter states that no RQ's were exceeded
101551

2007-12-07
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: VERY COMMON INCIDENT: See notes to 07-04399
101394

2007-12-01
Heaters and boilers
Cause: unplanned shut down of the D-SRU and the loss of an amine pump at one of the circulators

Followup: Yes

Notes: CITGO follow-up letter states that the heaters and boilers did not exceed their emission limits by an RQ amount. Letter does not specify whether they exceeded the limits at all.
101359

2007-11-30
Sulfuric Acid Plant
Cause: routine start

Followup: No

Notes: CITGO letter states that no RQ's were exceeded
101229

2007-11-24
JC-36 Topper Tail Gas Compressor
Cause: flaring sour tail gas during unexpected shut down of JC-

Followup: No

Notes: CITGO letter states that no RQ's were exceeded
101225

2007-11-23
B-12 Flare
Cause: loss of JC1A Compressor at unicracker unit

Followup: No

Notes: CITGO letter states that no RQ's were exceeded
101206

2007-11-21
Sulfuric Acid Plant
Cause:

Followup: No

Notes: Verbal report indicates delayed notification of emission because there is a new person working the console. Release occurred during routine start up of Sulfuric Acid Plan
101177

2007-11-20
Cooling Towers 1 and 2
Cause: tube leak in E-12 overhead condenser, C-175D at the C-4 Recovery Un

Followup: No

Notes: The backpressure controller set point was changed from 217 to 210 PSIG. The alarm settings will be changed to a lower setting to prevent Operations from running the tower at such an elevated pressure.
6,517.0 pounds
100759

2007-11-04
Lube and Wax Plant Flare
Cause: failed PSV release to CLAW flare

Followup: No

Notes: CITGO letter states that no RQ's were exceeded
100672

2007-10-31
A-Topper Unit at the B-7 Flare ; Feed Prep Unit at the B-6 Flare
B-6 Flare ; B-1 Furnace
Cause: see not

Followup: No

Notes: emissions result from flaring of residual materials in preparation for planned turnarounds
100672

2007-10-31
A-Topper Unit at the B-7 Flare ; Feed Prep Unit at the B-6 Flare
B-6 Flare ; B-1 Furnace
Cause: see not

Followup: No

Notes: emissions result from flaring of residual materials in preparation for planned turnarounds
99829

2007-09-28
Lube and Wax Vacuum Unit BA-1 and BA-101 Furnaces
Cause: see notes

Followup: Yes

Notes: high levels of hydrogen sulfide fuel gas used during production caused elevated levels of sulfur dioxide in the emissions. DEQ does air monitoring, notes concentration of 2.9 ppm upwind of the facility. Follow-up reports state that past data was inaccurate and that CITGO is meeting the 2000 ppm emission limit from the furnace stack. It is not clear if the post-hoc analysis they present has real bearing on the emissions from the stackat the time of the inciden
99160

2007-09-02
Central Amine Unit ; Sulfur Recovery Units
Cause:

Followup: No

Notes: Upset of Central Amine System and Sulfur Recovery Unit yields high H2S levels in the refinery's fuel gas
98928

2007-08-25
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: VERY COMMON INCIDENT: See notes to 07-04399
98774

2007-08-17
Lube Plant Flare
Cause: Vacuum II Un

Followup: No

Notes: Fire caused by mechanical seal failure at the Lube Plant Flare resulating from shutdown of Vacuum II Unit
98659

2007-08-14
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: VERY COMMON INCIDENT: See notes to 07-04399
98548

2007-08-09
B-7 Flare ; B-8 Flare
Cause:

Followup: No

Notes: B-7 flaring stems from shutdown of the JC-51 Compressor at the FCCUs; B-8 flaring stems from upset at C4 Recovery Unit
98367

2007-08-03
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: Same incident cause as 07-04040 of 07/19/2007 and 07-02449 of 5/12/2007 and 07-02284 of 05/05/2007
07-BB006-1119

2007-07-23
Sulfuric Acid Plant
Cause:

Followup: No

Notes: Emissions occurred during routine startup of Sulfuric Acid Plant
97961

2007-07-19
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: CITGO reports emissions as below RQ
97649

2007-07-06
Sulfuric Acid Plant
Cause:

Followup: No

Notes: Emission occurred during routine start up of Sulfuric Acid Plant
96817

2007-06-05
Sulfuric Acid Plant
Cause:

Followup: No

Notes: Emissions occurred during routine startup of Sulfuric Acid Plant
96768

2007-06-04
B-7 Flare 3(IX)33 ; Sulften absorber vent at Sulfur Recovery Unit 3(XX-H)1 ; TGII Absorber Vent at Sulfur Recovery Unit 3(XX-J)5 ; furnaces and boilers ; sweet crude oil pipeline to Tank 101
Cause: short duration rain event; swirling winds 60mph+, hail and lightning - see notes - see not

Followup: Yes

Notes: The storm caused a loss of power at Substation 21 and power blips on lines from Entergy impacting the Sulfur Recovery Plant. CITGO believes water entered the Substation via a the joint b/w the roof and the side wall causing a fused switch failure. Loss of power resulted in higher pressure and increase in liquid levels causing flaring at B-7. Loss of amine flow and hydrogen sulfide absorption generated heavy smoking from some of the boiler stacks and upset the Sulfur Recovery Plant. Operations pnnel inadvertently overloaded the Central Amine Unit causing high SO2 emissions throughout the Refinery. The crude oil leak was caused by internal corrosion. Limited offsite impact from soot from smoking boilers. REMEDIAL ACTIONS --> A Root Cau
237,471.0 pounds
96739

2007-06-03
B-7 Flare
Cause:

Followup: No

Notes: Flaring occurred during shut down of the B-Topper Unit
96337

2007-05-17
B-9 Flare
Cause: No information given

Followup: No

Notes: Emission through B-9 Flare resulted from depressuring contents of a sour gas line from Coker 2 to the flare. No reason for this depressuring is cited.
96183

2007-05-14
Unit Stack Sulfur Dioxide Analyzer
Cause: heavy rainfall with extensive lightning; analyzer disabled by lightning strike

Followup: No

Notes: Letter mentions sulfur dioxide and hydrogen sulfide but does not cite emission of Sulfur Trioxide, which is listed in the attached verabl repor
96170

2007-05-13
B-5 flare
Cause: depressuring a propane condensate line to the flare from the Oil Movement Area

Followup: No

Notes: propane transfer line removed for repair causes incident; De-pressuring to on-site refinery flare. Remedial action, if any, unclea
96145

2007-05-12
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: Verbal report states that loop seal had blown but not been reported by prior shift at the time of the seal failure. Relieved pressure on the drum causing it to reseal.
95932

2007-05-05
JC-2 Recycle Compressor
Cause: unexpected trip of the JC-2 Recycle Compressor caused the shutdown of the Unicracker Unit

Followup: Yes

Notes: Since Unicracker unit was shut down as result of this incident, CITGO will keep case no. open until unit is returned to servic
95938

2007-05-05
B-11 Flare
Cause: SEAL or GASKET - loss of a water seal on the blowdown system at the Coker 2 Unit

Followup: No

Notes: Conflict between letter and incident report: letter indicates that all emissions were BRQ; report says SO2 was >1000lbs. No offsite protective action despite emission of material offsite.
95799

2007-05-01
Sulfuric Acid Plant
Cause: routine start

Followup: No

Notes:
95491

2007-04-19
B-Topper Unit, B-7 Flare
Cause:

Followup: No

Notes:
95348

2007-04-13
E-Sulfur recovery Unit (E-SRU)
Cause: no information giv

Followup: No

Notes:
94948

2007-03-28
Sulfuric Acid Plant
Cause: no information giv

Followup: No

Notes: second Sulfuric Acid Plant incident in four days
94896

2007-03-26
Coker 1 Unit; F201A Drum; B5 Flare
Cause: Unit upset and the flaring of process gas

Followup: No

Notes:
94866

2007-03-25
Sulfuric Acid Plant
Cause:

Followup: No

Notes:
94548

2007-03-11
Sulfuric Acid Plant
Cause: start up of Sulfuric Acid Plant after unscheduled turnarou

Followup: No

Notes:
94517

2007-03-09
E-10 debutanizer tower
Cause: startup of debutanizer tower in c4 Light Ends Recovery Uni

Followup: No

Notes: Verbal report indicates that there was a grass fire on the Equistar property across from the BLCOH Control Room. This incident involved three separate flares, lasting a total of 1 h 41 mins. The flares resulted from multiple causes, each of which was related to the malfunction of the E-10 debutanizer tower. The two separate grass fires burned for a total of 2 h 54 m. The letter of 3/16/07 from Citgo states that the emissions limits were not exceeded; however, the DEQ incident report indicates NOxemissions totaled 122 lbs, exceeding the 24 hour limit of 10 lb
969.0 pounds
94446

2007-03-08
EIV valve J-36 Topper Tail Gas compressor
Cause: leaking emergency isolation valve on the J36 Topper Tail gasket

Followup: No

Notes:
94381

2007-03-05
A-Sulfur Recovery Unit
Cause: start up of A-Sulfur Recovery Unit from a planned turnarou

Followup: No

Notes: verbal report indicates that poisonous gas went offsite but no offsite protective action was taken; follow-up report on 4/16 indicates Citgo began implementation of six remedial tactics listed in the C-SRU Taill Gas Alternate Disposition Project Study on 4/10/07.
4,580.0 pounds
94384

2007-03-05
B-601 Furnace at the Sulfuric Acid Plant
Cause: Plugged burner tip at B-601 Furnace

Followup: No

Notes:
93978

2007-02-15
B-12 Flare pilot - Unicracker unit
Cause: pump seal fire and flare pilot outage at the Unicracker Unit

Followup: No

Notes:
93789

2007-02-07
Coker 1 Unit
Cause: Unit upset and the flaring of process gas

Followup: No

Notes:
93473

2007-01-25
Lube and Wax Plant Duosol unit
Cause: Unit upset and the flaring of process gas

Followup: No

Notes: Claims emission was below RQ; verbal report indicates that Terry Chretien of Citgo insists that the release had not gone off site even though it was a release to air.
93277

2007-01-14
flange on C-4 recovery unit
Cause: flange leak during a blind installation for a planned turnaround of the C-4 Recovery Unit

Followup: No

Notes: No information given
93243

2007-01-12
B-7 Flare
Cause: shut down for planned turnaround of York System and parts of the C-4 Recovery Uni

Followup: No

Notes:
111418

2008-12-14
Unicracker Unit
Cause: see notes

Followup: No

Notes: Flash fire in the Unicracker Unit
110375

2008-10-27
B-7 Flare
Cause: No information given

Followup: No

Notes: verbal report mentions C4 Recovery Unit, JC101 Compress
109953

2008-10-09
Acid Plant
Cause:

Followup: No

Notes: routine start up of acid plant; no release documented at time of report, verbal report serves as prospective notificati
109637

2008-09-29
B-12 Flare
Cause:

Followup: No

Notes: A-SRU experience swings in air demand caused by hydrocarbon carryover from the A Sour Water Tower (E301A). Flow from E-301 to A-SRU was stopped, then restarted. Startup was cause of release. Stopped again. Another start up released even more SO2. REMEDIAL ACTIONS: Upgrade existing suge tank skim oil pumps, Add third surge tank skim oil pump, install instrumentation to detect hydrocarbons in SWS feed
20,000.0 pounds
109022

2008-09-13
B-11 Flare, B-12 Flare, Sulften Stack, C-Cat Scrubber,
Cause: Hurricane Ike

Followup: Yes

Notes: Power Failure causes release of huge amount of S02. Loss of Pecan Grove substation caused the loss of power to equipment in the SRU, Central Amine, cid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II Units. Combustion efficiencyof 99% was used to calculate S02 emissions - is that an appropriate figure? Follow-up report on 10/27/2008 discusses emissions from B-11 Flare only REMEDIAL ACTIONS - perform feasability study of reliable power supply for acid block ; Install nsary equipment to start up JC-201 Compressor with less than RQ Flare Emissio
82,889.0 pounds
108489

2008-09-02
E-SRU
Cause:

Followup: No

Notes: Start up of E-Sulfur Recovery unit; no further info given about reason for start up
108247

2008-08-21
Refinery
Cause: see notes

Followup: No

Notes: Power Failure
107212

2008-07-15
Sulften Vent EQT297 ; Tail Gas II Stack EQT 298
Cause:

Followup: No

Notes: Some pollutants released onto Highway, which was sealed off during clean up. 5.5 inches of rain in a 3 hour period led to depressurization in process units and various instrumentation problems; event met or approached the 25-year 3-hour intensity standard; Install three additional sumps, pumps, and associated piping in the steam trench to alleviate flooding during heavy ra
1,000.0 pounds
107166

2008-07-13
CVEP Unit
Cause: No information given

Followup: No

Notes: Fire in the CVEP Unit
106702

2008-06-25
B-1 Flare (EQT343), B-5 Flare (EQT345), B-7 Flare (EQT347), B-12 Flare (EQT 351), B-16 Flare (EQT352)
Cause: see notes

Followup: Yes

Notes: Power Failure resulting from excessive moisture and dirt accumulation in switchgear breaker cubicle ; inadequaet physical clearance b/w insulators covering energized components; REMEDIAL ACTIONS: Clean and inspect all switchgear ; Eliminate practical spaces that allow air infiltration in or out of the switchgear room; modify switchgear purchase specifications to prohibit insulating material covering energized conductors to come in contact with materials from other phases; Modify QA-380-5045 tspect for insulating boots from adjacent phases to be in contact with one another; Verify other Powerhouse switchgear does not contain insulating boots that are in contact with one another; Install local temp and humidity monitors in rm, install anal
6,400.0 pounds
106297

2008-06-09
Acid Plant
Cause:

Followup: No

Notes: Start up of the acid plant
106260

2008-06-07
B-5 Flare
Cause:

Followup: No

Notes: Valve leak in ALCOH Unit
106048

2008-05-31
Acid Plant
Cause: no information giv

Followup: No

Notes: CITGO letter states that emissions were BRQ
105979

2008-05-27
Acid Plant
Cause: no information giv

Followup: No

Notes: CITGO letter states that emissions were BRQ
105868

2008-05-22
Acid Plant
Cause: no information giv

Followup: No

Notes: CITGO letter states that emissions were BRQ
105367

2008-05-05
B-5 Flare, B-11 Flare
Cause: see notes

Followup: No

Notes: Release results from depressuring of a propane line to the flares
105059

2008-04-24
Heaters and Boilers
Cause: see notes

Followup: No

Notes: release results from combustion of treated refinery fuel gas containing higher than normal concentrations of hydrogen sulfide
104545

2008-04-07
B-7 Flare
Cause: combusting excess treated refinery fuel

Followup: No

Notes: CITGO letter states that emissions were BRQ
104028

2008-03-18
Sulfuric Acid Plant
Cause: routine startup of Sulfuric Acid Pla

Followup: No

Notes: CITGO letter states that emissions were BRQ
103985

2008-03-15
B-5 Flare
Cause: start up of Coker 1 Un

Followup: No

Notes: Letter states that emissions did not exceed permitted limits by an RQ amount - does not specify how much was emitted though, or if the amount exceeded the permitted limit
103360

2008-02-22
B-6 Flare
Cause: shutdown of Topper Tail Gas Compressor JC36 for maintenan

Followup: No

Notes: CITGO letter states that the emissions were BRQ
103287

2008-02-21
B-12 Flare
Cause: loss of JP3 Feed Pump Motor at the Unicracker Unit

Followup: No

Notes: CITGO letter states that the emissions were BRQ
102969

2008-02-10
B-5 Flare
D-SRP, A-SRP, C-SRP
B-7 Flare
B-9 Flare
B-12 Flare
B-6 Flare
Cause: power outage

Followup: Yes

Notes: Partial power outage: Powerhouse System feeder cable 444-PH-FR13004 faulted in a Y-splice in manhole 26. bad cable resulted in loss of interconnection of Powerhouse generators and Entergy utility power. Caused collapse of electric and steam generation systems. Protective relay miscoordination is another cause. Root Cause Failure Analysis submitted 3/25/2008 indicates that startup of three Sulfur Recovery Units results in large emissions of sulfur dioxide. REMEDIAL ACTIONS: Revise Construction Inspen QA/QC procedure for PILC cable/splice installation to include additional clarification of detail; Repair 444-PH-FR13004 ; Perform a complete reevaluation of of protective relay coordination for all breakers assoc'd with Powerhouse main buses; I
62,701.0 pounds
102799

2008-02-04
Sour C3 Mix Pipeline
Cause: leak in the Sour C3 Mix Pipeline and the blowdown of the pipeline to the flare

Followup: Yes

Notes: According to first letter, RQ for flammable gas likely exceeded and RQ for Sulfur Dioxide possibly exceeded. Follow-up says all was B
102678

2008-01-29
Sulfuric Acid Plant
Cause: routine startup of Sulfuric Acid Pla

Followup: No

Notes: CITGO letter states that the emissions were BRQ
102569

2008-01-25
Sulfuric Acid Plant
Cause: routine startup of Sulfuric Acid Pla

Followup: No

Notes: CITGO letter states that the emissions were BRQ
102040

2008-01-01
B-7 Flare
Cause: trip of the JC-101 compressor at the C4 Recovery Unit

Followup: No

Notes: CITGO letter states that the emissions were BRQ
120411

2009-12-24
B-16 flare
Cause: No RQs were exceeded, so no information was given.

Followup: No

Notes: Flaring of sour gas from the Ultra Low Sulfur Diesel Hydrotreating unit's flare. No RQs were exceeded, so no information was given.
120457

2009-12-19
Acid plant
Cause: Power failure in acid plant area.

Followup: No

Notes: No RQs were exceeded, so no information was given.
119770

2009-12-01
Acid plant
Cause: No RQs were exceeded, so no information was given.

Followup: No

Notes: No RQs were exceeded, so no information was given.
119709

2009-11-25
B-11 flare
Cause: No RQs were exceeded, so no information was given.

Followup: No

Notes: No RQs were exceeded, so no information was given. Report to the police states that Hydrogen Sulfide and Nitrogen Oxides as well.
119256

2009-11-04
B-4 Flare
Cause: No RQs were exceeded, so no information was given. Release related to loss of flare flame on the B-4 flare.

Followup: No

Notes: No RQs were exceeded, so no information was given.
118715

2009-10-14
No information given
Cause: Accident related to shutdown of the Acid Plant. No RQs were exceeded so no further information is given.

Followup: No

Notes: No RQs were exceeded so no information is given.
118282

2009-09-29
No information given
No information given.
Cause: No RQs were exceeded so no further information is given.

Followup: No

Notes: No information given
118082

2009-09-21
E-3 tower
Cause: Flaring of sour gas from the E-3 Tower in the straight run fractionation unit. No RQs were exceeded so no further information was given.

Followup: No

Notes: No information given. State police report also reports butane released in addition to Sulfur Dioxide.
117561

2009-08-27
E-8 Tower, Flare
Cause: Flaring of sor gas from the E-8 tower in the C4 Recovery Unit. No RQs were exceeded so no further information was given.

Followup: No

Notes: No information given
115685

2009-06-14
B-5 Flare
Cause: No RQs were exceeded, so no information was given.

Followup: No

Notes: No information given
115661

2009-06-13
No information given
Cause: No RQs were exceeded so no information was given.

Followup: No

Notes: no information given
114679

2009-05-04
B-8 flare
Cause: BLCOH unit compressor pressure relief valve lifted releasing hydrogen sulfide, nitrogen oxide and sulfur dioxide into the B-8 flare

Followup: No

Notes: gases burned in flare and release "secured"
115679

2009-05-04
B-8 flare
Cause: BLCOH unit compressor pressure relief valve lifted releasing hydrogen sulfide, nitrogen oxide and sulfur dioxide into the B-8 flare

Followup: No

Notes: gases burned in flare and release "secured"
113969

2009-04-05
B-5
Cause: B-5 flare

Followup:

Notes: no information given
113121

2009-03-04
Process Unit
Cause: start up of Acid plant

Followup: No

Notes: CITGO determined that no RQ's were exceeded, therefore no remedial action was taken.
112786

2009-02-16
B-16 flare in Ultra Low Sulfur Diesel Unit
B-16 flare at Ultra Low Sulfur Diesel Unit
Cause: Sour Gas flare from the B-16 flare caused by the lifting of a pressure relief valve in the Ultra Low Sulfur Diesel unit at CITGO Lake Charles Manufacturing plant.

Followup:

Notes: No information given.
128390

2010-12-29
FLARE: Flare B-11 & B-12; Coker 2 Unit
Cause: "...they shutdown a gas compressor at the coker 2 unit due to liquid in a drum....An unknown amount of hydrogen sulfide and sulfur dioxide was released to the flare." FLARE.

Followup: No

Notes: BRQ. Refinery letter states that no reportable quantities were exceeded. No additional information given.
123898

2010-06-02
B-12 flare
Cause: G8 filter over-pressurized while being warmed and went to B12 flare.

Followup: No

Notes: no information given
123765

2010-05-26
B7 flare
Cause: Leaking relief valve from the B Catcracker Unit caused additional material to go to flare.

Followup: No

Notes: no information given
123702

2010-05-23
B12 flare
Cause: Lost a compressor in process unit, chemicals released to flare--no details.

Followup: No

Notes: Spare compressor was put on
123188

2010-05-02
B12 flare
Cause: The JC 1C Compressor over-pressurized causing relief valve to open to B-12 flare.

Followup: No

Notes: No information given
122816

2010-04-15
no information given
Cause: Power surge tripped equipment in acid plant when Entergy lost a transformer.

Followup: No

Notes: BRQ. Refinery letter states that no reportable quantities were exceeded. Stabilized plant but still having problems. No additional information given.
122547

2010-04-03
#7 flare
#7
Cause: smoke coming out of flare from unknown source--no more details given--no RQs exceeded

Followup: No

Notes: no information given
122264

2010-03-21
B6 flare
Cause: JC-36 compressor shut down, caused line to overpressurize and release to flare.

Followup: No

Notes: No information given. SPOC and refinery letter only. No LDEQ report.
122168

2010-03-17
B-12 flare
Cause: Swapping out compressors, overloaded system, valve released to flare

Followup: No

Notes: no information given
121535

2010-02-17
FLARE: B8 flare
Cause: relief valve at the C4 unit released sending sour hydrocarbons to the B8 flare. FLARE.

Followup: Yes

Notes: no info given
121160

2010-01-30
FLARE: B12 flare
Cause: unicracker unit shut down--high temperature on a D3 reactor resulted in a 100lb system opening up causing materials to be released to flare File contains no DEQ report, only refinery letter with no details of incident indicating it is ongoing and under investigation. Specific calculations promised in follow-up letter to be sent by 2/28/10.

Followup: No

Notes: air monitoring inside & outside perimeter
135517

2011-11-23
Acid Plant Unit
Cause: A leak was located in the acid plant unit.

Followup: No

Notes: The unit was shut down immediately upon discovery of the leak and the leaking section of the line was repaired.
1,948.0 pounds
132764

2011-08-01
Fired heaters and boilers
Sulfen Vent Stack EQT297, Tail Gas II Vent Stack EQT298, B-7 Flare
B-7 Flare EQT347
Sulften Vent Stack, Tail Gas II Vent Stack
Cause: The operator failed to manually reset the solenoid valve that controlled the level in the F-104 drum prior to restarting the JC-102 compressor. Based on the definition of control equipment inLAC 33:III.1 1 1, Citgo failed, in this incident, to diligently maintain control equipment in proper working order whenever emissions were being made. That initial failure to reset the solenoid valve cause a string of upsets, which began with the central amine upset.

Followup: Yes

Notes: Immediate corrective actions taken were removing excess hydrocarbon from the central amine unit, amine feed to the SRUs was reduced, and efforts were made to identify the hydrocarbon source. Citgo conducted an incident investigation, which outlines several actions to be taken. Additional letters from refinery regarding this incident: 8/18/11, 10/27/11
2,354.0 pounds
132807

2011-07-30
FLARE-Ultra-low Sulfur Diesel hydrotreater, B-16 flare
Cause: Ultra-low Sulfur Diesel Hydrotreater (USLD) unit upset led to unplanned shutdown and flaring.

Followup: No

Notes: BRQ. No information given regarding remedial actions. No LDEQ report included. Notified the SPOC 24:36 after incident occured.
131653

2011-06-05
Unicracker unit
Cause: LDEQ report states that power was lost to the Unicracker unit resulting in a flare.

Followup: No

Notes: BRQ: Quantities of hydrogen sulfide and sulfur dioxide were below reportable quantities. No further information on remedial actions was given.
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
159.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
768.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
3,169.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
63,701.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
7,921.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
5,055.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
303.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
474.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
4,999.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
18,174.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
4,037.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
2,176.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
5,445.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
294.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
571.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
307.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
824.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
441.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
2,191.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
1,862.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
2,073.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
689.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
9,080.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
11,091.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
3,922.0 pounds
130780

2011-04-26
Acid Plant
SRF Unit (B-5)
Feed Prep (B-101)
HP Boilers (8-1C, 8-1, 8-1A, B-2a, B-3c, 8-5A)
CVEP unit (8101A, 81018, 8102A, 81028)
Vacuum (8-2A, 8-201)
Unicracker unit (B-1,2,3,4,5)
A Reformer (B-101)
A Reformer (B 102-106)
B Reformer (B 401-406)
ALCOH unit (B 101-103)
BOH unit ( B 601,602)
Sulfolane unit (B-201, 202)
ISOM unit (B-801)
Coker 2 unit (B-201, 202)
A Cat unit (B-2, 6)
B Cat unit (B-2, 6)
C Cat unit (B-2, 6)
Ultra Low unit (B-101, 102)
A-CGH unit (B 101-103)
B-CGH (B 201- 203)
BLCOH unit (B-101, 3)
A Topper unit (B-4)
B Topper unit (B-104)
C Topper unit (B-1C, 2C)
Coker 1 unit
Cause: Due to a thunderstorm, a loss of electrical power from the Pecan Grove substation caused the shutdown of the Sulfur Recovery Unit (SRU), Central Amine, Acid Plant, Sour Water Stripper, Unicracker, Wastewater Treating and Coker II units. An incident investigation was initiated, scheduled to be completed June 10, 2011.

Followup: Yes

Notes: According to the second follow-up Refinery Letter, CITGO: 1) Contacted Entergy for power restoration 2) reduced refinery/unit charge rates Area was monitored and all parameters measured zero. Investigation to be completed by 6/10/2011. Report of regarding this investigation is not available.
6,762.0 pounds
129988

2011-03-17
Sour Gas Line
Cause: State police report states that there was a leak in a three inch line under a relief valve at the vacuum unit. Product of the release was sour gas and went off-site.

Followup: No

Notes: BRQ. Line was blocked and repaired. Air monitoring was performed in the plant area, and no readings were indicated.
129836

2011-03-13
FLARE: JC101 Compressor to B7 Flare
Cause: FLARE. State police report states that C-4 recovery unit JC101 compressor tripped and vented to the B7 Flare. Chemicals burned out in the flare.

Followup: No

Notes: BRQ. Refinery letter states that a "review of operating data showed that no reportable quantities were exceeded." Refinery letter and SPOC report only. No LDEQ report.
129671

2011-03-06
FLARE: B11 and B12 Flare
Cause: FLARE. State police reports states that fill pressure of the flared gas recovery system was exceeded and resulted in flaring from the B11 and B12 flares. No root cause is known. Material went off-site through the flare and then air.

Followup: No

Notes: BRQ. No Information Given. Refinery letter and SPOC report only. No LDEQ report.
129077

2011-02-06
C-Cat PC152 Instrument
Cause: State police report states that the C-Cat PC152 instrument failure caused over-pressurization of the E1 Fractionator.

Followup: No

Notes: BRQ. Refinery letter states that "review of operating data showed that no RQ were exceeded." Pressure was relieved by releasing the hydrogen sulfide and sulfur dioxide to the B-7 Flare. Refinery letter and SPOC report only. No LDEQ report.
145571

2012-12-26
Coker 2 Unit
Cause: A compressor upset on the Coker 2 Unit caused the gases to go to the flare.

Followup: No

Notes: An unknown amount of sulfur dioxide, hydrogen sulfide, and nitrous oxide went to the flare as a result of this incident. Air monitoring was being preformed up to the fence line and readings are unknown at this time.
144156

2012-08-07
B-11 Flare
Cause: The Coker II unit gas compressor (JC-201) shutdown. Shutdown resulted in unit gas relieving to the B-11 flare. Specific cause of shutdown was under investigation until September 21, 2012.

Followup: No

Notes: Half of Coker II unit was shut down and unit feed rate reduced to minimum rate (feed rate reduced by two thirds). In addition, immediate repair was begun on the JC-201 compressor. Compressor JC-201 was repaired and compressor was restarted. Investigation team was assembled to conduct a root cause investigation of shutdown. Release calculations indicate that reportable quantities of sulfur dioxide and hydrogen sulfide were exceeded during this flaring event.
23,714.0 pounds
136319

2012-01-05
FLARE: Multiple flares coming from UNI Cracker, Coker 2, Acid Plant, and SRU

Cause: There was a total plant power failure. The UNI Cracker, Coker 2, Acid Plant, and SRU are all flaring.

Followup: No

Notes: The electrical problem was corrected and air monitoring took place.
149329

2013-06-20
B502 Reactor D-SRU
Thermal Oxidizer
Cause: On June 20, a release of hydrogen sulfide and sulfur dioxide into the air was caused by a small leak from the B502 Reactor furnace in the D-Sulfur Recovery Unit was discovered.

Followup: Yes

Notes: The unit was shut down and the leak was repaired. According to CITGO, a review of the operating data from this event showed that no RQs were exceeded, but the start-up of the unit resulted in emissions that exceeded the RQ of 500 pounds for sulfur dioxide. During startup after the incident on June 22, the unit sent tail gas to the thermal oxidizer while heating up the catalyst beds with natural gas. Sulfur dioxide emissions during this time was 1818 pounds. Pursuant to Paragraph 93a of the NSR Consent Decree, stipulated penalties shall not apply to a tail gas incident attributable to the scheduled start-up of an individual train at the SRP located at the Lake Charles Refinery, provided that CITGO demonstrates that it has implemented good air pollution control practices.
149329

2013-06-20
B502 Reactor D-SRU
Thermal Oxidizer
Cause: On June 20, a release of hydrogen sulfide and sulfur dioxide into the air was caused by a small leak from the B502 Reactor furnace in the D-Sulfur Recovery Unit was discovered.

Followup: Yes

Notes: The unit was shut down and the leak was repaired. According to CITGO, a review of the operating data from this event showed that no RQs were exceeded, but the start-up of the unit resulted in emissions that exceeded the RQ of 500 pounds for sulfur dioxide. During startup after the incident on June 22, the unit sent tail gas to the thermal oxidizer while heating up the catalyst beds with natural gas. Sulfur dioxide emissions during this time was 1818 pounds. Pursuant to Paragraph 93a of the NSR Consent Decree, stipulated penalties shall not apply to a tail gas incident attributable to the scheduled start-up of an individual train at the SRP located at the Lake Charles Refinery, provided that CITGO demonstrates that it has implemented good air pollution control practices.
1,818.0 pounds
160197

2014-11-23
Crude Vacuum Unit (CV-1)
Cause: Release of sulfur dioxide (SO2) due to a flaring event at CITGO's Crude Vacuum Unit (CV-1). The incident occurred due to a brief power outage at an electrical substation for the unit. The duration of the flaring event was 13 minutes.

Followup: No

Notes: No information provided on remedial actions taken
160105

2014-11-15
Dock A
Cause: Explosion occurred in the last 30 minutes of loading a sulfur barge at Dock A. Explosion ignited a small (approximately 30 square feet) grass fire on the west side of Dock A. Citgo then stated that no reportable quantities were exceeded during the event.

Followup:

Notes: Fire was extinguished
156031

2014-05-17
B-1 Heater (C Topper Unit)
Cause: A Fire occurred inside of the B-1 Heater (C Topper Unit) due to tube leak.

Followup: No

Notes: The fire was quickly secured. No reportable quantities or permit limits were exceeded during the release.
153833

2014-02-11
furnaces
Cause: On Feburary 12, CITGO Lake Charles Manufacturing Complex notified LDEQ's Single Point of Contact of a sulfur dioxide release that occurred on February 11, 2014 at 20:18 hrs. According to Phyllis Holifield, Manager of Environmental Protection Department, stated that an amine pump tripped out in the Fuel Gas Processing Unit stopping the amine flow for 4 minutes which lead to the release of sulfur dioxide from various furnaces in the unit.

Followup: No

Notes: State Police notification report states that amine pump was turned back on and functioning in the normal range of operation.