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ExxonMobil Refinery (2638), Baton Rouge

Causal Factor: Weather

LDEQ Accident Number
Accident Date
Point Source(s) Notes Amount of Release
No LDEQ Reported

2007-07-05
tank 263
Cause: STORMS- styrene that is not permitted to be stored in tank in the east area south field tanks were emitted while stored in these tanks.

Followup: No

Notes: LCCO is being removed from tank 263 (usual incident number not listed, LAC number given instead); this could have been preventable and the Refinery could have reduced rates, however this was not considered prudent under the given circumstances
0.0000029

0.000002288
0.00000047




Volatile Organic Compounds: 211.0 pounds


97285

2007-06-02
failed system
Cause: STORMS-Heavy rains(air blower system failed)

Followup: Yes

Notes: Airflow to the furnace was reestablished.
Carbon Monoxide: 36,625.0 pounds
95874

2007-05-03
Leak-process sewer leak
Cause: STORMS-Heavy rains(surrogate sewer needed for storm water diversion)

Followup: Yes

Notes: The excavated sewer line will be repaired. During rain shoring in excavation was damaged and shoring must be repaired before permanent sewer repairs commence.
Primary Sludge: 14.0 pounds
108690

2008-09-05
Flare
Cause: STORMS-startup brought on flaring after rapid shutdwon due to Hurricane Gustav

Followup: Yes

Notes: refinery is undergoing startup operations. All efforts are being made to minimize environmental impacts. A follow up report will be submitted when startup flaring has ended.
Hydrogen Sulfide: 3,806.0 pounds
Nitrogen Dioxide: 36,505.0 pounds
Sulfur Dioxide: 368,396.0 pounds
Ammonia: 312.0 pounds
108484

2008-09-02
FLARE-Sour Water Stripper routed to flare
Cause: STORMS-Hurricane Gustav

Followup: No

Notes: no information given
Sulfur Dioxide: 506,946.0 pounds
Nitrogen Oxide: 1,797.0 pounds
Nitrogen Dioxide: 72,037.0 pounds
Volatile Organic Compounds: 12,228.0 pounds
Hydrogen Sulfide: 5,496.0 pounds
Ammonia: 618.0 pounds
108485

2008-09-01
FLARE- All 8 flares
FLARE-All 8 flares
Cause: STORMS-Hurricane Gustav

Followup: No

Notes: Refinery was safely and sytematically shutdown due to the hurricane. Learning from this even will be incorporated into future hurricane preparations.
Sulfur Dioxide: 28,656.0 pounds
Nitrogen Oxide: 1,314.0 pounds
Nitrogen Dioxide: 225.0 pounds
Volatile Organic Compounds: 7,690.0 pounds
Propylene: 174.0 pounds
108721

2008-09-01
Atmospheric release
Cause: STORMS-Hurricane Gustav

Followup: No

Notes: no information given
Methyl Ethyl Ketone: 22,698.0 pounds
MIBK(Methyl Isobutyl Ketone): 5,675.0 pounds
107396

2008-07-19

Cause: Oil sheen was seen after rain.

Followup: No

Notes: LDEQ report stated excavation in refinery area, after rain saw an oil sheen on water in hole (cat naptha)oi

105626

2008-05-15
outfall #1 system
Cause: Due to heavy rains, outfall #1 system discharged an oily material into the Mississippi River.

Followup: No

Notes: The spill was below the reportable quantity, so no written report was submitted by ExxonMobil.

103806

2008-03-11
spill
Cause: Dirt stored in wast management area was leached through by the rain.

Followup: No

Notes: All oil that leaked into parking lot was removed and contaminated soil was removed and disposed properly. Additional barrier was created around Waste Management area to contain oily residue.

No LDEQ Reported

2009-12-08
Outfall 003
Cause: The large volume of water after a heavy rainfall resulted in an oil sheen. Oil was release through Outfall 003 into bayou. The size and color of the sheen indicated a release of less than 1/4 gallon of oil.

Followup: No

Notes: Release is BRQ.
Oil: 0.3 pounds
116811

2009-07-27
Oil-Water Separator
Cause: Due to heavy rainfall, the Oil-Water Separator at QAL overflowed.

Followup: No

Notes: RQ exceeded. Vacuum truck and absorbent pads recovered the material. Contaminated soil was disposed of. Tank levels will be monitored more closed in the future.
F037 Hazardous Waste: 15.0 pounds
116531

2009-07-15
Outfall 003
Cause: There was a rain storm that lasted 1 hour and 15 minutes and produced 3.5 inches of rain. During this time, an estimated 1/8 of a gallon of oil was released into the treatment system and thus spilt through Outfall 003 into Callahan's Bayou. The oil sheen was 20'x30' and dissolved as it went with the current.

Followup: No

Notes: RQ not exceeded.
Oil (Sheen): 0.1 pounds
128383

2010-12-30
Outfall 003
Cause: ExxonMobil received over 3 inches of rain in an eight hour period during the evening of 12/29/10, and this large volume and intensity of water resulted in an oil sheen. Material was released through Outfall 003 into Mississippi River via Callahan's Bayou. The size and color of the sheen indicated a release of approximately .25 gallons of oil per National Oceanic and Atmospheric Administration sheen estimating guidance.

Followup: No

Notes: Sheen boomed off & cleaned up. Additionally, boom at Callahan's Bayou that was found broken was replaced. Duration of release was approximately 1h 40m from discovery to cleanup completion. This incident will be reviewed through the Refinery's stormwater compliance program, STOP (Sewer Tracking and Oil Prevention) to evaluate responses to future potential rainstorms.
Oil: 0.3 gallons
128030

2010-12-07
No Information Given
Cause: The cold weather may have prevented the gas from reaching the compressor and caused the flare to burn which released sulfur dioxide.

Followup: No

Notes: The LDEQ incident report says that an estimated 500 pounds of sulfur dioxide was released due to flaring. This amount is reportable quantity. However, the refinery letter states that no releases exceeded reportable quantity.

120699

2010-01-10
vacuum jet on vapor recovery system
Cause: Vacuum jet that keeps the vapor recovery system failed due to cold weather. Benzene vented to atmosphere intermittently and restarted once thawed. Written report states that block in fuel gas line due to subfreezing temperatures resulted in back pressure on blowdown drum which blew intermittently its atmospheric seal. HCE vacuum jet sends vapors from several tanks in Aromatics unit to this blow down drum ( BD-106) and resulted in tank venting to atmosphere. Amount of Benzene released from these two sources is 66 lb.

Followup: No

Notes: Release exceeds RQ. Exxon thawed liquid line, vacuumed liquid away and restarted jet. Steps in place to eliminate freeze points and restore flare gas pressure. LABB only has access to State Police and LDEQ reports.
Benzene: 66.0 pounds
120701

2010-01-10
leaking pipe
Cause: Benzene spill possibly due to pipe leaking in freezing weather.

Followup: No

Notes: No Refinery letter. LDEQ report indicates refinery filed a report with State Police detailing the event, but it's not included in the file.

Wastewater: 20.0 gallons
120677

2010-01-09
unspecified piping
Cause: Discharge piping on pump had freeze related damage.

Followup: No

Notes: Release is below reportable quantities.


120611

2010-01-08
flare
Cause: Over pressure to flare due to cold weather. LDEQ indicates it is a safety issue and flared with smoke. No information given as to amounts of releases.

Followup: No

Notes: LABB only has access to LDEQ incident report. No information provided if release was BRQ.




132835

2011-07-31
Furnace 1
Cause: Initial reports indicate that lighting struck furnace 1 and the fire went out and smoked for 11 minutes.

Followup: No

Notes: Less than 1 pound of PAHs were released which is BRQ.
Polycyclic Aromatic Hydrocarbons: 1.0 pounds
142046

2012-08-11
Rain Basin 2 - Outfall 003
Cause: A heavy rainfall event occured resulting in Rain Basin 2 to overlflow through Outfall 003 into Callahan's Bayou and then into the Mississippi River. The sheen was approximately 50ft X 30ft, and the volume released was less than 2 cups of oil. ExxonMobil deployed additional containment boom immediately upon an employee's discovery of the sheen. Investigation efforts to determine root cause analysis are still under investigation.

Followup: No

Notes: Upon discovery boom was deployed to contain and absorb the sheen. Investigation efforts to identify root cause of oil are inconclusive. ExxonMobil will continue to monitor for potential oil in sewers and collection system to detect and mitigate potential spills. Upset description states that the River Basin 2 overflow through the Outfall 003 started on August 9, 2012 at 17:57 hours and continued until cessation on August 12, 2012 at 20:06 hours. Thus, the overflow occurred for 3 days, 2 hours, 9 minutes.
Oil (Sheen): 0.1 gallons
137359

2012-02-18
FLARE: Flare #7
Cause: Excessive rainfall caused an electrical ground fault to occur with some of the compressor's control instrumentation causing the three compressors to shut down. excesses gases were released to the flares.

Followup: No

Notes: Air monitoring occurred and eventually two of the three compressors were brought back on-line and flaring ceased. There is no refinery Incident report and no SPOC report attached to this file.
Sulfur Dioxide: 18,333.0 pounds
Hydrocarbon: 2,069.0 pounds
Highly Reactive Volatile Organic Compounds (HRVOCs): 167.8 pounds
Propylene: 156.1 pounds
Hydrogen Sulfide: 147.6 pounds
Nitric Oxide: 1,404.8 pounds
Volatile Organic Compounds (VOCs): 6,421.8 pounds
Ethylene: 112.0 pounds
Nitrogen Dioxide: 1,069.0 pounds
Benzene: 10.4 pounds
Butadiene: 10.3 pounds
No LDEQ Reported

2013-01-09
Outfall 003
Cause: On January 9, 2013 at the ExxonMobil Baton Rouge Refinery a heavy rainfall event occurred resulting in Rain Basin 2 to overflow through Outfall 003 into Callahan Bayou. Between January 8, 2013 and January 10, 2013, ExxonMobil received approximately 6.2 inches of rain. At approximately 12:35 p.m. an ExxonMobil employee at the Dock discovered an oil sheen coming from Callahan Bayou.

Followup:

Notes: The size and color of the sheen were used to estimate the total release of oil based on the National Oceanic and Atmospheric Administration (NOAA) sheen estimating guidance. Approximately one cup of oil was released. Upon discovery, boom was deployed to isolate the source of oil. Vacuum trucks have been utilized to skim the Refinery's #2 Rain Basin of oil.
Oil: 0.1 gallons
156260

2014-05-28
Refinery Outfall 003
Cause: 2 Incident numbers; the second is 14-02336 3 inches of rain caused an oil sheen to escape the Refinery's outfall and enter the Mississippi River via Callahan's Bayou. Sheen was 100ft by 20ft and light silver in color.

Followup: No

Notes: The incident will be reviewed through the refinery's storm water compliance system. Hard and absorbent boom were used to collect the oil. Amount of oil spilled was calculated using the National Oceanic and Atmospheric Administration (NOAA) sheen estimating guidance.
Oil: 0.1 gallons
156261

2014-05-28
Stormwater Outfall 003
Cause: Exxon received over three inches of rain. This volume resulted in oil exiting the refinery's Stormwater Outfall 003, entering the Mississippi River through Callahan's Bayou and creating a sheen. Sheen was approximately 20 ft by 100 ft.

Followup: No

Notes: Sheen was cleaned up by hard absorbent boom. This incident will be reviewed through the Refinery's storm water compliance program STOP (Sewer Tracing and Oil Prevention) to evaluate responses to future rainstorms.
Oil: 0.1 gallons
No LDEQ Reported

2014-04-07
Rain Basin #2
Cause: A severe thunderstorm on 4/7/2014 resulted in Rain Basin 2 overflowing through Outfall 003 into Callahan Bayou. An ExxonMobil operator discovered an oil sheen coming from Callahan Bayou. The size and color of the sheen were used to estimate the total release of oil based on the National Oceanic and Atmospheric Administration sheen estimating guide.

Followup: No

Notes: Upon discovery, boom was deployed to contain the sheen. Vacuum trucks have been used to skim the refinery's #2 Rain Basin of oil.
Oil: 0.1 gallons