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Chalmette Refining (1376), Chalmette

Causal Factor: Start Up, Shut Down

LDEQ Accident Number
Accident Date
Point Source(s) Notes Amount of Release
78541

2005-04-26
Sulfur Recovery Unit, Hydrocracker, #2 Coker, #2 Crude
Cause: A loss of power to the Refinery's Boiler Instrumentation System caused the shutdown of the three plant boilers which generate the Refinery's 600 lb. steam. The loss of 600 lb. steam production caused upset conditions at a series of Refinery Process Units including the Sulfur Recovery Unit, Hydrocracker, #2 Coker and #2 Crude

Followup: No

Notes: The refinery has initiated an investigation into the cause of this incident. Based on the result of that investigation, measures will be taken in order to prevent a recurrence due to the same cause. The report's Summary of Emissions also states 692 lbs. of HC, 1131 lbs of CO, and 36 lbs of PM were also released at this time.
Hydrogen Sulfide: 203.0 pounds
Nitric Oxide: 326.0 pounds
Nitrogen Dioxide: 36.0 pounds
Sulfur Dioxide: 79,817.0 pounds
76869

2005-02-11
No information given
Cause: Power failure caused many of the processes to shut down.

Followup: No

Notes:
Carbon Monoxide: 93.0 pounds
Hydrocarbon: 65.0 pounds
Hydrogen Sulfide: 1.0 pounds
Particulate Matter: 17.0 pounds
Nitrogen Dioxide: 1.0 pounds
Nitric Oxide: 6.0 pounds
Sulfur Dioxide: 454.0 pounds
76775

2005-02-04
Electrical breaker G-457; Waste gas compressor number 2 (K-401)
Cause: Electrical breaker for G-457 malfunctioned, unexpectedly cutting power to all pumps and fin-fans within the refinery waste gas compressor area. Waste gas compressor number 2 (K-401) shut down as a result of the electrical power outage and refinery waste gas was diverted to safety flare system.

Followup: No

Notes: Low-Sulfur content streams were routed to the flare to minimize sour gas flaring. Output was adjusted to minimize total amount of waste being sent to the flare. Note: the breaker for G-457 had been identified for repair and was supposed to be replaced that week.
Carbon Monoxide: 78.0 pounds
Hydrocarbon: 51.0 pounds
Hydrogen Sulfide: 11.0 pounds
Particulate Matter 10: 3.0 pounds
Nitrogen Dioxide: 1.4 pounds
Nitric Oxide: 13.0 pounds
Sulfur Dioxide: 4,075.0 pounds
76382

2005-01-24
Waste gas compressor shut down and caused an over pressure situation
Cause: Waste gas compressor shut down and an over-pressure situation.

Followup: No

Notes: Rescinding notification for below reportable quantities. (There is a hand-written T76382 on incident # 76355 PDF, but LABB believes that they are unrelated).
Carbon Monoxide: 46.0 pounds
Hydrocarbon: 24.0 pounds
Nitric Oxide: 8.0 pounds
Nitrogen Dioxide: 1.0 pounds
Sulfur Dioxide: 0.9 pounds
92940

2006-12-29
Waste Gas Compressor
Cause: Waste Gas System Compressor shut down due to water contamination of the oil in the crank case.

Followup: No

Notes: Rates at the HDS and CFHT units were reduced and CRLLC routed sweet hydrocarbons streams to the flares to minimize flaring. Oil was drained from the crank case and replaced. The K-406 Compressor was restarted.
Sulfur Dioxide: 31,282.0 pounds
Volatile Organic Compounds (VOCs): 1,370.0 pounds
92642

2006-12-14
Flare No. 2 EPN 29
Cause: Crude 2 K-7601 Compressor shut down

Followup: No

Notes: Machinists restarted the compressor and an investigation of the incident is underway.
Sulfur Dioxide: 3,236.0 pounds
92412

2006-12-04
#1 Flare
#2 Flare
Cause: shut down of interstage cooler causing trip of WGC

Followup: No

Notes: Resetting alarms to appropriate levels; reinforced training of the operators on WGS operations at low temperatures.
Nitrogen Oxide: 6.0 pounds
Sulfur Dioxide: 1,946.0 pounds
90535

2006-09-08
#1 Flare - AE-AOA-05-0109 EPN 28
Cause: during Coker 1 startup the top of the fractionator tower flooded due to an unstable flow from the heavy gas Oil pump around (typical during startup). The end result was an overpressure to the emergency flare system.

Followup: No

Notes: the k-2800 will be reconnected to the Number 2 Flare for use in emergency situations only until the FGR System is commissioned. Communication to employees on what constitutes and emergency situation will occur.
Sulfur Dioxide: 1,005.0 pounds
Nitrogen Oxide: 10.0 pounds
84697

2006-08-02
AE-AOA-05-0109 EPN 46
Cause: loss of instrument air pressure resulting in upset and shutdown of multiple process units within the refinery. Resulted from July 31, 2006 upset and the resultant restart and passivation of SRU Train 2

Followup: No

Notes: refinery has initiated an investigation into the cause
Sulfur Dioxide: 3,173.0 pounds
89293

2006-07-17
AE-AOA-05-0109 EPN 29
Cause: the process of startup and shutdown of the FCC resulting in apparent variability of FCC to Alky feedstock product quality with accumulation of noncondensable materials. Personnel allowed a controlled partial depressurization to avoid overpressure.

Followup: No

Notes: this incident will be reviewed by FCC and Alky process team leaders in order to increase awareness of the potential impacts of FCC shutdown/startup operations on Alky feed composition.
Nitric Oxide: 23.0 pounds
89266

2006-07-14
Flare
Cause: compressor shut down on the Hydrocracker Unit

Followup: No

Notes: Letter written to rescind notification of 7/14/6
Nitric Oxide: 2.0 pounds
87763

2006-05-11
Flare
Cause: light ends sent to flare during start up

Followup: No

Notes: Letter written to rescind notification of 5/11/6

86878

2006-03-31
Emergency Flare System AE-AOA-05-0109 EPN 29
Cause: waste gas compressors 4 and 3 (K406 and 402) automatically shut down, lowering the refinery capacity and causing overpressure to the emergency flare system. Liquid level pump (G476) switch was in the off position.

Followup: No

Notes: A mechanical guard was placed on the pump switch in order to avoid the unintentional movement of the switch
Sulfur Dioxide: 3,174.0 pounds
86612

2006-03-20
Emergency Flare System AE-AOA-05-0109 EPN 29
Cause: compressor 1(K-400) automatically shut down, lowering waste gas processing capacity and causing overpressure to the emergency flare system. Later, waste gas compressor number 2 (K-401) automatically shut down causing the waste gas system to further overpressure to the emergency flare system.

Followup: No

Notes: the refinery has initiated an investigation, appropriate measures will be taken in order to prevent a recurrence due to the same cause.
Sulfur Dioxide: 2,204.0 pounds
85953

2006-02-21
AE-AOA-05-0109
Cause: during startup of liquefied Petrol. Gas compressor, an unexpected liquid was present in the compressor discharge piping. This caused an unexpected upset resulting in over pressurization of the refinery fuel system. No. 2 Flare.

Followup: No

Notes: the refinery has initiated an investigation, appropriate measures will be taken in order to prevent a recurrence due to the same cause.
Nitric Oxide: 25.0 pounds
101671

2007-12-13
None Reported
Cause: lost gas compressor K-8111; unit vented to flare

Followup: No

Notes: No information given
100423

2007-10-22
Emergency Flare System
Cause: Number 1 Coker Wet Gas Compressor shutdown on high amperage when water entrained in the feed line to the compressor caused the compressor to overheat.

Followup: No

Notes: Operators closed the valve to the feed line to the compressor and restarted the K-2800 compressor. The line was again dewatered and lined back up to the compressor K-2800 without shutting down the compressor.
Sulfur Dioxide: 958.0 pounds
100358

2007-10-20
Emergency Flare System
Cause: incident occurred during shut down of the Sulfur Recovery Unit train 1 for maintenance. Train 2 also shut down, initiating release.

Followup: No

Notes: Operators restarted Train 2 twice before they were able to route acid gas through Train 2 and out of the Emergency Flare System ending the flaring.
Sulfur Dioxide: 211,810.0 pounds
Hydrogen Sulfide: 566.0 pounds
100315

2007-10-19
Emergency Flare System
Cause: Train 2 shut down due to low oxygen flow

Followup: No

Notes: Operators restarted Train 2 to end the flaring.

Sulfur Dioxide: 12,020.0 pounds
98704

2007-08-16
# 3 reformer debutanizer tower
Cause: The LEP absorber tower was shutdown & the #3 debutinizer tower could not send overhead vapor to the LEP therefore #3 towerincr. and PSV was exceed. PSV on the # 3 reformer debutanizer tower reached the PSV set pressure causing a release. The LEP was shutdown due to an unstable steam rate.

Followup: No

Notes: The feed rate was reduced to the units to stop the release until the PSV was reseated and confirmed not leaking. Follow up letter indicates that human factors also played a role; an operator did not respond appropriately to a series of alarms.
Volatile Organic Compounds: 6,362.0 pounds
98528

2007-07-01
#2 Flare
Cause: a third-party hydrogen provider, Air Products, was shut down, followed by the shut down of Louis Dreyfus, limiting ability of CRLLC to minimize flaring

Followup: No

Notes: CRLLC maintains open communication lines with third-party providers to reduce the impact of any third party upsets that result in supply shortages.
Benzene: 36.0 pounds
98527

2007-06-29
#2 Flare
Cause: a third-party hydrogen provider, Air Products, was shut down, followed by the shut down of Louis Dreyfus, limiting ability of CRLLC to minimize flaring

Followup: No

Notes: CRLLC maintains open communication lines with third-party providers to reduce the impact of any third party upsets that result in supply shortages.
Benzene: 20.0 pounds
95937

2007-05-04
No information given
Cause: shut the compressor down due to potential for significant refinery upset

Followup: No

Notes: Letter written to rescind notification of 5/4 concerning release of hydrocarbons

94538

2007-03-11
Waste Gas Compressor
Cause: The WGC tripped due to low seal oil pressure

Followup: No

Notes: the charge rates on the #2 coker WGC were cut. The turbine main pump was restarted and is running in parallel with the auxiliary electric pump.
Sulfur Dioxide: 659.0 pounds
110843

2008-11-18
#1 Flare
Cause: start up of the alkylation unit

Followup: No

Notes: Letter states that emissions were BRQ.

110719

2008-11-09
None Reported
Cause: scheduled shut down of the alkylation unit

Followup: No

Notes: Letter states that emissions were BRQ.
108881

2008-09-07
None Reported
Cause: Flaring due to refinery start up

Followup: No

Notes: DEQ report sans corresponding CRLLC letter
117083

2009-08-06
SRU 1 and 2
Cause: Sulfur Recovery Unit Train (SRU 2) shutdown due to a steam excursion in the refinery. The steam excursion had caused the SRU 2 to shutdown from low boiler water level. The acid gas loading from SRU 2 was added to SRU 1 which caused the emissions. A second incidence occurred when the refinery lost its hydrogen supply from Air Products. This caused the shutdown of the refinery hydrotreaters and a significant decrease in refinery acid gas production. SRU 1 shutdown due to the insufficient acid gas leading to a second emission.

Followup: Yes

Notes: acid gas was routed from SRU 2 to SRU 1. Acid gas flaring was avoided and DGA strippers was contained until SRU 1 was restarted. SRU 1 was run at minimal air flow rates to avoid excess H2S consumption due from insufficient acid gas rates. Caustic addition was maximized in tail gas section to mitigate additional SO2 formation.
Sulfur Dioxide: 1,136.0 pounds
114850

2009-05-09
HDS unit
Cause: HDS unit leak on outlet of E3301. Shut down to do repairs causing release..

Followup:

Notes: RQ not exceeded.
Volatile Organic Compounds: 198.0 pounds
Hydrogen Sulfide: 8.0 pounds
132188

2011-07-09
No Information Given
Cause: Planned unit shutdown for maintenance operations.

Followup: No

Notes: BRQ: According to the Refinery Letter, "unit operations and shutdown timing were adjusted to minimize environmental impact."
Sulfur Dioxide: 1,949.0 pounds
Volatile Organic Compounds (VOCs): 146.0 pounds